Upstream Catalyst Layer for Gas Phase Oxidation Hot Spot Control

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Solution Overview

Problem

In gas phase oxidation of aromatic hydrocarbons, existing catalyst systems face issues with hot spots forming unevenly, leading to side reactions, catalyst deactivation, and reduced yield and selectivity over time, due to uneven catalyst activity and migration of hot spots, which limits the service life and increases the risk of uncontrollable reactions.

Innovation Solution

A catalyst system with two or more catalyst layers, where the upstream layer is either inert or less active with a smaller volume and higher surface area-to-volume quotient, arranged in a specific configuration to rapidly heat the reaction gases and position the hot spot closer to the reactor inlet, reducing the risk of uncontrollable reactions and extending catalyst service life.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If the catalyst activity in the first layer is increased to improve reaction rate, then productivity increases, but hot spot temperature becomes uncontrolled and selectivity decreases

Engineering Contradiction:
Improvereaction rateVSAvoidselectivity
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent applies local quality by creating distinct zones within the catalyst bed: the first catalyst layer has high activity for rapid reaction initiation, while subsequent layers have progressively lower activity to control hot spot temperature. This spatial variation in catalyst properties allows each zone to perform its specific function - the first layer maximizes productivity while downstream layers maintain selectivity by preventing excessive temperature rise.

Inventive Principle:
Principle #3Local quality

2Duration of action of stationary object

If the catalyst activity decreases with operating time, then the reaction shifts towards the reactor outlet and hot spot migrates downstream, but product yield significantly decreases

Engineering Contradiction:
Improvecatalyst service lifeVSAvoidproduct yield
Core Design Contradiction:
Duration of action of stationary objectVSProductivity

Solution Approach 1:

The patent implements preliminary action by pre-positioning multiple catalyst layers with different activities before operation begins. As the first layer deactivates over time, the reaction naturally transitions to subsequent layers that were pre-configured with appropriate activity levels. This ensures that even as operating time increases, the hot spot remains confined to the first layer or transitions predictably to downstream layers, maintaining product yield throughout the catalyst's service life.

Inventive Principle:
Principle #10Preliminary action

3Productivity

If the temperature of the heat transfer medium is increased to counteract catalyst deactivation, then reaction rate improves, but hot spot temperature increases and causes over-oxidation and side reactions

Engineering Contradiction:
Improvereaction rateVSAvoidside reactions
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The patent applies parameter changes by varying the catalyst activity parameter across different layers rather than changing the heat transfer medium temperature. The first layer uses high activity catalyst to maintain reaction rate, while downstream layers use lower activity catalysts to inherently limit temperature rise. This approach allows the system to maintain productivity through catalyst design rather than temperature control, avoiding the harmful side reactions that would result from increasing heat transfer medium temperature.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration allows for quicker reaction initiation, positions the hot spot further towards the inlet, reducing side reactions and maintaining high yield and selectivity, while ensuring safer operation and longer catalyst service life by controlling the hot spot formation and migration.

Implementation Method 1

The heat released during the chemical reaction heats the reaction gas to the point where the energy generated by the reaction is just as great as the energy given off to the coolant

Methodology Applied
Scientific EffectExothermic reaction: Exothermic Reaction

Implementation Method 2

the pipes are surrounded by a heat transfer medium, for example molten salt

Methodology Applied
Scientific EffectHeat transfer: Heat Exchanger

Data Source

PatentEP2106290B1Catalyst system and method for gas phase oxidation using an upstream layer
Publication Date: 2016.04.13 BASF SE
  • EP2106290B1 patent drawingFigure 1A~1B

AI summary

The present invention relates to a method for gas phase oxidation, wherein a gaseous flow comprising aromatic hydrocarbon and molecular oxygen is conducted through two or more catalyst layers. The present invention further relates to a catalyst system for gas phase reaction using an upstream layer. The product of diameter times the height, or the volume, of the inert and/or catalyst rings disposed upstream is less than at least one of the subsequent catalyst layers, or the quotient of the surface per volume of the upstream inert and/or catalyst rings is greater than at least one of the subsequent catalyst layers.