Urea Acid Complex Dimensional Stability Solid Fillers

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Solution Overview

Problem

Conventional solid compositions using urea and acid are limited by stability issues, leading to dimensional instability and performance deficiencies in cleaning, sanitizing, and rinsing applications, particularly due to high water content and unfavorable interactions with additional active components.

Innovation Solution

A stable solid urea/acid complex is formed, which includes quaternary ammonium compounds and surfactants, providing a dimensionally stable matrix that maintains performance and can be formulated for various cleaning applications, including warewashing and floorcare, through a process that overcomes the limitations of conventional acid fillers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If liquid acid is used in solid compositions, then acid functionality is provided, but water content increases and dimensional stability deteriorates

Engineering Contradiction:
Improvedimensional stabilityVSAvoidwater content
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The patent uses solid acid fillers (such as calcium carbonate, silica, or alumina) as intermediary substances to replace liquid acid in the solid composition. These solid fillers provide the necessary acid functionality and buffering capacity without introducing excess water, thereby maintaining dimensional stability while delivering acid-based cleaning and sanitizing effects.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention changes the physical state parameter of the acid from liquid to solid form by using solid acid fillers. This parameter change allows the composition to maintain low water content and high dimensional stability while still providing the required acid functionality for cleaning and sanitizing applications.

Inventive Principle:
Principle #35Parameter changes

2Stability of the object's composition

If urea and acid are combined in solid compositions, then solidification is achieved, but stability issues arise leading to dimensional instability

Engineering Contradiction:
Improvecomposition stabilityVSAvoiddimensional stability
Core Design Contradiction:
Stability of the object's compositionVSShape

Solution Approach 1:

The patent creates a composite solid composition combining urea, solid acid fillers, and additional active components in a stable matrix. This composite structure ensures that the urea and acid coexist stably without causing dimensional instability, while maintaining the functionality of all components including quaternary ammonium compounds and surfactants.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

Solid acid fillers serve as intermediary substances that mediate between urea and other active components in the composition. These fillers provide structural support and chemical stability, preventing unwanted reactions between urea and acid while maintaining dimensional stability of the solid composition during storage and use.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Adaptability or versatility

If additional active components are added to urea/acid compositions, then functionality is enhanced, but interaction instability increases

Engineering Contradiction:
ImprovefunctionalityVSAvoidinteraction stability
Core Design Contradiction:
Adaptability or versatilityVSStability of the object's composition

Solution Approach 1:

Solid acid fillers act as intermediary substances that stabilize interactions between urea and additional active components such as quaternary ammonium compounds and surfactants. These fillers prevent unwanted chemical reactions and maintain the stability of the composition while allowing multiple functional components to coexist and work together effectively.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention formulates a stable composite material containing urea, solid acid fillers, and multiple active components including quaternary ammonium compounds and surfactants. This composite structure ensures compatibility and stability among all components while providing enhanced functionality for cleaning, sanitizing, and rinsing applications.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The stable urea/acid complex ensures exceptional dimensional stability and performance in cleaning, sanitizing, and rinsing applications, maintaining stability under kinetic and thermodynamic conditions, and allowing for broader acid compatibility, including high solubility acids, while retaining actives effectively.

Implementation Method 1

stable solid compositions comprising urea and an acid... form a solid complex as a solidification matrix

Methodology Applied
Scientific EffectComplex formation: Chemical Bonding

Data Source

PatentUS20240415117A1Mechanism of urea/solid acid interaction under storage conditions and storage stable solid compositions comprising urea and acid
Publication Date: 2024.12.19 ECOLAB USA INC
  • US20240415117A1 patent drawing
  • US20240415117A1 patent drawing
  • US20240415117A1 patent drawing

AI summary

Solid rinsing, cleaning and/or sanitizing compositions for various applications are provided. In particular, solid compositions include a complex of urea and an acid having desirable storage stability previously unavailable in solid urea/acid compositions. Stable solid compositions are disclosed and methods of making the same to overcome conventional limitations associated with forming kinetically and thermodynamically stable solids that utilize urea/acid compositions.