Thermoformable Dielectric Composition for Moisture-Safe Silver Circuits

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Solution Overview

Problem

Existing dielectric materials are not effectively used as moisture barriers during thermoforming procedures in capacitive switches, particularly when highly conductive silver is involved, leading to potential moisture interaction and substrate damage, such as cracking or crazing in polycarbonate substrates.

Innovation Solution

A polymer thick film moisture barrier layer dielectric composition comprising thermoplastic urethane resin, thermoplastic phenoxy resin, diacetone alcohol, and fumed silica, which provides a printable and thermoformable layer that protects polycarbonate substrates from moisture penetration and ensures compatibility with conductive silver layers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional dielectric materials are used as moisture barriers during thermoforming procedures, then the substrate may be damaged (cracking or crazing in polycarbonate), but the electrical elements are not adequately protected from moisture

Engineering Contradiction:
Improvemoisture protectionVSAvoidsubstrate damage
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent uses a composite dielectric material comprising thermoplastic urethane resin, thermoplastic phenoxy resin, diacetone alcohol, and fumed silica. This composite formulation provides both moisture barrier properties and substrate compatibility, preventing both moisture penetration and substrate damage during thermoforming procedures

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the dielectric material composition by incorporating specific ratios of thermoplastic urethane resin (10-50 wt%), thermoplastic phenoxy resin (10-50 wt%), diacetone alcohol (1-20 wt%), and fumed silica (0.1-5.0 wt%). These parameter changes enable the material to simultaneously provide moisture protection and prevent substrate damage

Inventive Principle:
Principle #35Parameter changes

2Reliability

If highly conductive silver is used in capacitive circuits, then electrical performance is improved, but moisture interaction with the silver conductor causes degradation

Engineering Contradiction:
Improveelectrical conductivityVSAvoidmoisture interaction
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The dielectric composition acts as an intermediary protective layer between the highly conductive silver and moisture. The thermoplastic urethane resin, thermoplastic phenoxy resin, and fumed silica create a barrier that prevents moisture from reaching the silver conductor while maintaining the electrical performance of the circuit

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The composite dielectric material provides both moisture barrier properties and electrical insulation, protecting the highly conductive silver from moisture interaction while maintaining circuit performance

Inventive Principle:
Principle #40Composite materials

3Reliability

If a moisture barrier dielectric layer is added to protect silver conductors, then moisture protection is improved, but the complexity of the circuit construction increases

Engineering Contradiction:
Improvemoisture barrier protectionVSAvoidcircuit construction
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The dielectric composition serves multiple functions simultaneously: it provides moisture barrier protection, electrical insulation, and substrate protection during thermoforming. This multi-functionality reduces the need for additional separate protective layers, thereby limiting the increase in construction complexity

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition effectively prevents moisture penetration, maintains substrate integrity, and enhances the longevity of capacitive circuits by reducing resistance changes under accelerated aging conditions, as demonstrated by comparative experiments.

Implementation Method 1

a first organic medium comprising 10-50 wt % thermoplastic urethane resin dissolved in an organic solvent

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Implementation Method 2

mitigates moisture penetration

Methodology Applied
Scientific EffectPermeation: Permeation

Implementation Method 3

0.1-5.0 wt % fumed silica

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 4

1-20 wt % diacetone alcohol

Methodology Applied
Scientific EffectSolvation: Solvation

Data Source

PatentUS8785799B1Moisture barrier layer dielectric for thermoformable circuits
Publication Date: 2014.07.22 DU PONT CHINA LTD

AI summary

This invention is directed to a polymer thick film moisture barrier layer dielectric composition comprising thermoplastic urethane resin, thermoplastic phenoxy resin, diacetone alcohol and fumed silica. Dielectrics made from the composition can be used in various electronic applications to protect electrical elements and particularly to insulate and protect both the conductive thermoformable silver above it and the polycarbonate substrate below it in capacitive switch applications.