UV Curable Polyurethane Acrylate Coating for Anti-Steel and Hardness

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Solution Overview

Problem

Current UV curable coating compositions exhibit poor anti-steel properties, as evidenced by significant differences in contact angle before and after steel wool testing, necessitating an improvement in fingerprint resistance, anti-steel performance, and hardness.

Innovation Solution

A UV curable coating composition comprising a high-functionality UV curable polyurethane acrylate with a functionality of 6 or more, combined with 0.1-3 wt.% fluorine-containing acrylic soil-repellent, and comprising 5-50 wt.% of six-functionality and ten-functionality aliphatic polyurethane acrylates, which enhances abrasion resistance and maintains contact angle stability after steel wool testing.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional UV curable coating compositions are used, then the coating provides basic protective properties, but the anti-steel property is poor with significant contact angle difference before and after steel wool testing

Engineering Contradiction:
Improveanti-steel propertyVSAvoidcontact angle stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent changes the chemical composition parameters by incorporating fluorine-containing acrylic soil-repellent (0.1-3 wt.%) and high-functionality polyurethane acrylates (5-50 wt.% six-functionality and 5-50 wt.% ten-functionality) to improve contact angle stability and anti-steel properties while maintaining UV curability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite coating system combining fluorine-containing acrylic soil-repellent with high-functionality polyurethane acrylates (6-functional and 10-functional) to achieve synergistic effects that simultaneously improve anti-steel property, contact angle stability, fingerprint resistance, and hardness

Inventive Principle:
Principle #40Composite materials

2Strength

If high functionality polyurethane acrylate is used to improve hardness and anti-steel, then abrasion resistance increases, but formulation complexity increases

Engineering Contradiction:
Improveabrasion resistanceVSAvoidformulation complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent optimizes the functionality parameter of polyurethane acrylate to 6 or 10, and controls the weight percentage ranges (5-50% for six-functionality and 5-50% for ten-functionality) to achieve high abrasion resistance while managing formulation complexity through defined compositional parameters

Inventive Principle:
Principle #35Parameter changes

3Reliability

If fluorine-containing acrylic soil-repellent is added to improve fingerprint resistance, then soil repellency increases, but the coating composition complexity increases

Engineering Contradiction:
Improvefingerprint resistanceVSAvoidcoating composition complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent adds fluorine-containing acrylic soil-repellent at a controlled concentration of 0.1-3 wt.% to provide fingerprint resistance and soil repellency while minimizing composition complexity through precise dosage control

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent integrates fluorine-containing acrylic soil-repellent into the polyurethane acrylate-based coating matrix to create a composite formulation that provides fingerprint resistance without significantly increasing overall formulation complexity

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides a coating with improved fingerprint resistance, high anti-steel properties, and high hardness, maintaining a stable contact angle and excellent abrasion resistance, suitable for substrates like PMMA, PC, and PET, while being environmentally friendly and suitable for rapid curing.

Implementation Method 1

UV curable coating composition having fingerprint resistance, high anti-steel and high hardness... UV curable coating composition comprising a high-functionality UV curable polyurethane acrylate

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Implementation Method 2

0.1-3 wt.% of a fluorine-containing acrylic soil-repellent... improved fingerprint resistance... maintains a stable contact angle

Methodology Applied
Scientific EffectHydrophobic effect: Hydrophobe

Data Source

PatentEP3562898B1UV curable coating composition, method of applying the same and substrate coated therewith
Publication Date: 2023.06.07 PPG COATINGS TIANJIN

AI summary

A high-hardness anti-steel wool UV curable coating composition comprises a high-functionality UV curable polyurethane acrylate. A method of coating a substrate with the high-hardness anti-steel UV curable coating composition and the substrate coated with the same are also provided.