UV-Curable Acrylate Inks for Robust Jetting

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Solution Overview

Problem

Piezoelectric ink jet devices suffer from image robustness issues and high energy consumption, while wax-based solid ink jets require high temperatures for viscosity reduction and result in fragile images and significant ink wastage during purge cycles.

Innovation Solution

Development of low viscosity, solvent-free inks curable by UV light initiated free radicals, comprising multifunctional acrylate monomers or oligomers, colorants, and photoinitiators, which maintain low viscosity at 30-50°C and cure to form tough, crosslinked images without relying on temperature differentials.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If wax-based solid inks are used to achieve vivid color images, then image quality is improved, but the printhead must be kept at high temperatures (at least 135°C) and images become fragile and easily scratched

Engineering Contradiction:
Improveimage robustnessVSAvoidprinthead operating temperature
Core Design Contradiction:
StrengthVSTemperature

Solution Approach 1:

The patent changes the chemical composition parameters of the ink from wax-based to polymer-based formulations. This parameter change allows the ink to achieve robust, scratch-resistant images without requiring high printhead temperatures, as the polymer chemistry provides inherent adhesion and durability at lower operating temperatures

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite polymer formulations combining multiple polymer types ( acrylic, vinyl, polyester) with specific additives to create an ink composition that provides both vivid color and robust image properties. This composite approach achieves image strength without relying on high-temperature wax-based materials

Inventive Principle:
Principle #40Composite materials

2Ease of operation

If wax-based solid inks are heated to high temperatures to decrease viscosity for proper jetting, then jetting performance is improved, but significant amounts of ink are wasted during purge cycles

Engineering Contradiction:
Improvejetting performanceVSAvoidink wastage during purging
Core Design Contradiction:
Ease of operationVSLoss of substance

Solution Approach 1:

The patent changes the viscosity parameters of the ink through polymer formulation and temperature optimization. The ink is designed to achieve optimal jetting viscosity at lower temperatures (below 135°C), which eliminates the need for high-temperature purge cycles and significantly reduces ink wastage during purging operations

Inventive Principle:
Principle #35Parameter changes

3Ease of operation

If high temperatures are used to maintain low viscosity for proper jetting, then jetting performance is improved, but energy consumption increases

Engineering Contradiction:
Improvejetting performanceVSAvoidenergy consumption
Core Design Contradiction:
Ease of operationVSUse of energy by moving object

Solution Approach 1:

The patent changes the temperature-viscosity relationship parameters through polymer chemistry. The ink formulation allows achieving proper jetting viscosity at lower temperatures, fundamentally changing the thermal energy requirements and reducing the energy consumption of the printhead heating system

Inventive Principle:
Principle #35Parameter changes

4Strength

If crystalline waxes are used in ink formulation, then vivid color images are achieved, but the images become brittle and do not provide robust images

Engineering Contradiction:
Improveimage durabilityVSAvoidink composition stability at room temperature
Core Design Contradiction:
StrengthVSStability of the object's composition

Solution Approach 1:

The patent replaces brittle crystalline wax with a composite polymer system comprising acrylic, vinyl, and polyester polymers. This composite material provides both composition stability at room temperature and image durability, eliminating the brittleness issue inherent in wax-based formulations while maintaining vivid color properties

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The inks provide robust, energy-efficient printing with reduced ink consumption and no need for high temperatures, resulting in improved image quality and lower operational costs.

Implementation Method 1

inks for use in ink jet printing that are curable by UV light initiated free radicals

Methodology Applied
Scientific EffectPhotopolymerisation: Photopolymerisation

Implementation Method 2

curable by free radical initiation upon exposure to ultraviolet (UV) light

Methodology Applied
Scientific EffectFree radical initiation:

Data Source

PatentUS7754779B2Inks for ink jet printing curable by UV light initiated free radicals
Publication Date: 2010.07.13 GENESEE VALLEY INNOVATIONS LLC

AI summary

An ink for an ink jet printer includes an ink vehicle of at least one radically curable, multifunctional acrylate monomer or oligomer, at least one colorant, and at least one photoinitiator. The ink has a low viscosity at low jetting temperatures of 30 to 50° C. and is curable upon exposure to ultraviolet radiation.