UV Laser Diode Epitaxial Transfer With TCO Cladding

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Solution Overview

Problem

The development of high-quality, high-performance ultraviolet (UV) laser diodes has been hindered by issues such as excessive optical absorption in gallium nitride (GaN) substrates, strain-induced defects in aluminum gallium nitride (AlGaN) layers, and poor crystalline quality, leading to inefficiencies and material defects that limit the performance and lifetime of UV lasers.

Innovation Solution

A method involving the growth of thin n and p-type AlGaN cladding regions and active regions on native GaN substrates, followed by transferring the epitaxial structure to a carrier wafer with transparent conductive oxide (TCO) cladding layers, which reduces stress-induced defects and allows for the use of quaternary films to minimize strain, resulting in a high-quality AlGaN-based UV laser diode with low loss cladding and substrate materials.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If thin AlGaN cladding regions are grown on native GaN substrates, then manufacturing precision is improved, but strain-induced defects increase

Engineering Contradiction:
Improvecladding region qualityVSAvoiddefect density
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

A sacrificial layer is introduced as an intermediary between the GaN substrate and the AlGaN cladding regions. This sacrificial layer serves as a buffer that absorbs strain during the growth process, preventing strain-induced defects in the cladding regions. After the AlGaN layers are grown, the sacrificial layer is selectively removed, leaving a defect-free structure.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent employs selective area growth techniques where the growth parameters (such as temperature, pressure, and composition) are dynamically adjusted during the epitaxial process. By changing growth parameters in real-time, the patent optimizes the crystalline quality of AlGaN layers while managing strain accumulation, thereby reducing defects without compromising manufacturing precision.

Inventive Principle:
Principle #35Parameter changes

2Loss of energy

If transparent conductive oxide cladding layers are used, then optical absorption is reduced, but device complexity increases

Engineering Contradiction:
Improveoptical absorption lossVSAvoidstructure complexity
Core Design Contradiction:
Loss of energyVSDevice complexity

Solution Approach 1:

The patent utilizes transparent conductive oxides (TCOs) such as indium tin oxide (ITO) or zinc oxide (ZnO) as cladding layers. These TCO layers form a composite structure with the AlGaN active region, combining the optical transparency of oxides with the semiconductor properties of nitrides. This composite approach reduces optical absorption losses while maintaining electrical functionality, and the process integrates seamlessly with existing semiconductor fabrication techniques.

Inventive Principle:
Principle #40Composite materials

3Manufacturing precision

If quaternary films are used to minimize strain, then manufacturing precision is improved, but ease of manufacture decreases

Engineering Contradiction:
Improvestrain controlVSAvoidgrowth process difficulty
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The patent employs quaternary AlGaInN films with locally optimized composition profiles. By varying the aluminum and indium content at different positions and depths within the cladding regions, the patent achieves precise strain management. This local quality approach allows different parts of the structure to have tailored compositions that optimize both strain control and crystalline quality, despite the increased complexity of the growth process.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the production of high-quality UV laser diodes with reduced defects and improved efficiency by mitigating stress-induced issues and utilizing transparent conductive oxides to minimize optical absorption, thereby enhancing the performance and reliability of UV laser diodes.

Implementation Method 1

utilizing transparent conductive oxides to minimize optical absorption

Methodology Applied
Scientific EffectOptical absorption: Absorption (EM radiation)

Implementation Method 2

growth of thin n and p-type AlGaN cladding regions and active regions on native GaN substrates

Methodology Applied
Scientific EffectEpitaxy: Epitaxy

Data Source

PatentUS12126143B2Method of manufacture for an ultraviolet emitting optoelectronic device
Publication Date: 2024.10.22 KYOCERA SLD LASER INC
  • US12126143B2 patent drawing
  • US12126143B2 patent drawing
  • US12126143B2 patent drawing

AI summary

Methods for fabricating ultraviolet laser diode devices include providing substrate members comprising gallium and nitrogen or aluminum and nitrogen, forming an epitaxial material overlying a surface region of the substrate members, patterning the epitaxial material to form epitaxial mesa regions, depositing a bond media on at least one of the epitaxial mesa regions, bonding the bond media on at least one of the epitaxial mesa regions to a handle substrate, subjecting the sacrificial layer to an energy source to initiate release of the substrate member and transfer the at least one of the epitaxial mesa regions to the handle substrate, and processing the at least one of the epitaxial mesa regions to form the ultraviolet laser diode device.