UV LED Water Reactor with TiO2 Catalysts

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Solution Overview

Problem

Current groundwater cleanup techniques are costly, ineffective, and take years to decades to remediate contaminants such as chlorinated solvents, pharmaceuticals, and endocrine disrupting substances, posing risks of further environmental contamination with heavy metals and leached catalysts.

Innovation Solution

A reactor system using a fluoropolymer-coated vessel with ultraviolet light-emitting diodes (LEDs) and titanium dioxide-coated photo-catalyst substrates to degrade organic and biological contaminants, providing a more efficient, environmentally friendly, and portable solution for water remediation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If pump and treat technologies are used for groundwater cleanup, then some contamination removal is achieved, but the process is costly, ineffective, and takes years to decades to remediate

Engineering Contradiction:
Improveeffectiveness of contamination removalVSAvoidtime required for remediation
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The patent replaces mechanical pump and treat systems with a photochemical oxidation system using UV light and titanium dioxide photocatalysts. This substitution transforms the remediation mechanism from physical extraction to chemical degradation, achieving complete contaminant destruction rather than mere transfer to above-ground storage, thereby improving effectiveness and reducing treatment time.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the fundamental parameter of the remediation process by using photochemical reactions instead of mechanical pumping. The UV light wavelength, photocatalyst surface area, and reaction conditions are optimized to accelerate contaminant degradation kinetics, reducing the remediation timeframe from years to a much shorter period while maintaining high effectiveness.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If traditional photocatalysts are used, then contaminant degradation is achieved, but there is risk of environmental contamination from heavy metals and leached catalysts

Engineering Contradiction:
Improvecontaminant degradation effectivenessVSAvoidenvironmental contamination from heavy metals and catalysts
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent extracts and eliminates the harmful heavy metal components from traditional photocatalysts. By using titanium dioxide, a heavy metal-free material, the system maintains effective photocatalytic contaminant degradation while removing the source of secondary environmental contamination, thus resolving the contradiction between effectiveness and environmental safety.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent employs a stable, non-leaching titanium dioxide photocatalyst that can be easily replaced if needed, rather than using persistent heavy metal-based catalysts that pose long-term environmental risks. This approach prioritizes environmental safety while maintaining degradation effectiveness through the use of benign, disposable photocatalytic materials.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Reliability

If conventional UV systems are used, then disinfection is achieved, but energy consumption is high and portability is limited

Engineering Contradiction:
Improvedisinfection effectivenessVSAvoidenergy consumption
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The patent changes the UV light source parameter from conventional high-power lamps to energy-efficient UV LEDs. This parameter change maintains the necessary UV fluence rate for effective disinfection and photocatalytic activation while dramatically reducing power consumption, enabling portable applications and reducing operational costs.

Inventive Principle:
Principle #35Parameter changes

4Reliability

If conventional UV systems are used, then disinfection is achieved, but the systems are not portable and require extensive infrastructure

Engineering Contradiction:
Improvedisinfection effectivenessVSAvoidsystem portability and infrastructure requirements
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent replaces complex mechanical UV lamp systems with solid-state UV LED arrays, eliminating the need for bulky ballasts, high-voltage power supplies, and extensive cooling infrastructure. This substitution enables compact, portable reactor designs that maintain disinfection effectiveness while requiring minimal infrastructure, making the system suitable for field deployments and remote locations.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system effectively destroys at least 50% of contaminants, including bacteria and pharmaceuticals, producing potable water with reduced catalyst and energy consumption, and minimizing environmental risks.

Implementation Method 1

At least one ultraviolet light-emitting diode (LED) is included and disposed so as to project ultraviolet light into the reactor vessel

Methodology Applied
Scientific EffectLight-emitting diode (LED): Light Emitting Diode

Implementation Method 2

A plurality of photo-catalyst substrates are also disposed within the internal reactor volume of the reactor vessel. Each of these substrates includes a coating of titanium dioxide applied to an outer surface of a substrate

Methodology Applied
Scientific EffectPhoto-catalysis: Catalysis

Implementation Method 3

A fluoropolymer coating is applied over at least a portion of the interior surfaces of the reactor vessel

Methodology Applied
Scientific EffectFluoropolymer coating: Coatings

Data Source

PatentUS10793454B1Water treatment system with ultraviolet LEDs and photo-catalysts
Publication Date: 2020.10.06 THE GOVERNMENT OF THE UNITED STATES AS REPRESENTED BY THE SECRETARY OF THE AIR FORCE
  • US10793454B1 patent drawing
  • US10793454B1 patent drawing
  • US10793454B1 patent drawing

AI summary

A reactor system for treating contaminated water is disclosed. The reactor system includes a reactor vessel having first and second end portions and an internal reactor volume defined by interior surfaces of the reactor vessel. A fluoropolymer coating is applied over at least a portion of the interior surfaces of the reactor vessel. The reactor system also includes a water inlet disposed in the first end portion and a water outlet disposed in the second end portion. At least one ultraviolet light-emitting diode (LED) is included and disposed so as to project ultraviolet light into the reactor vessel. A plurality of photo-catalyst substrates are also disposed within the internal reactor volume of the reactor vessel. Each of these substrates includes a coating of titanium dioxide applied to an outer surface of a substrate. A method for remediating contaminated water is also disclosed.