UV-Sensing Microcapsules with Mixed Aromatic Solvents for Storage Stability

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Solution Overview

Problem

Existing ultraviolet-sensing sheets suffer from poor storage stability and image stability, particularly when exposed to hot or moist environments, leading to color formation issues and reduced color density.

Innovation Solution

The ultraviolet-sensing member incorporates a microcapsule containing a photoactivator, color-forming agent, and aromatic solvents with and without heteroatoms, with a specific mass ratio and boiling point, encapsulated in a resin capsule wall, to enhance stability and sensitivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If an ultraviolet-sensing sheet uses a capsule with color-forming agent and photooxidant, then the sheet can measure ultraviolet ray amount, but the sheet forms color in unused state when left in hot environment for long period

Engineering Contradiction:
Improvestorage stabilityVSAvoidcolor formation in unused state
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent changes the chemical composition parameters of the sensing layer by introducing a specific catalyst inhibitor and adjusting the ratio of photooxidant to color-forming agent. This resolves the contradiction by preventing unwanted color formation during storage while maintaining sensing functionality.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces a catalyst inhibitor as an intermediary substance that mediates between the photooxidant and color-forming agent, preventing premature reaction during storage while allowing controlled reaction during ultraviolet exposure.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Duration of action of stationary object

If the ultraviolet-sensing sheet is left in moist and heat environment after use, then the sheet can be stored, but the color density of colored part decreases

Engineering Contradiction:
Improveimage stabilityVSAvoidcolor density
Core Design Contradiction:
Duration of action of stationary objectVSQuantity of substance

Solution Approach 1:

The patent adjusts the chemical parameters of the sensing layer including the ratio of photooxidant to color-forming agent and adds a catalyst inhibitor to prevent degradation of color density in moist and heat environments during storage after use.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If the sensing layer contains only aromatic solvent without heteroatom, then the manufacturing is simple, but the storage stability and image stability are insufficient

Engineering Contradiction:
Improvestorage stability and image stabilityVSAvoidsolvent composition complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent creates a composite solvent system combining aromatic solvents with and without heteroatoms in specific ratios. This composite approach improves stability while maintaining reasonable manufacturing complexity through controlled composition.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides improved storage stability and image stability, ensuring accurate color formation based on ultraviolet exposure, with enhanced sensitivity and durability.

Implementation Method 1

a photoactivator, a color-forming agent, and an aromatic solvent... the aromatic solvent includes an aromatic solvent including a heteroatom and an aromatic solvent including no heteroatom

Methodology Applied
Scientific EffectPhotooxidation: Photo-oxidation

Data Source

PatentUS12372397B2Ultraviolet-sensing member, microcapsule, production method of microcapsule, dispersion liquid for forming ultraviolet-sensing layer, and ultraviolet-sensing kit
Publication Date: 2025.07.29 FUJIFILM CORP
  • US12372397B2 patent drawing
  • US12372397B2 patent drawing
  • US12372397B2 patent drawing

AI summary

A first object of the present invention is to provide an ultraviolet-sensing member having excellent storage stability and image stability. In addition, a second object of the present invention is to provide a microcapsule, a production method of a microcapsule, a dispersion liquid for forming an ultraviolet-sensing layer, and an ultraviolet-sensing kit. The ultraviolet-sensing member of the present invention is an ultraviolet-sensing member including an ultraviolet-sensing layer containing a microcapsule which contains a photoactivator, a color-forming agent, and an aromatic solvent, in which the aromatic solvent includes an aromatic solvent including a heteroatom and an aromatic solvent including no heteroatom.