UV-Shielding Composite Particles for Cosmetic Stability

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Solution Overview

Problem

Existing cosmetic materials face challenges in formulating effective ultraviolet-shielding products due to issues like allergic reactions from organic ultraviolet absorbents and difficulties in mixing inorganic and organic agents, particularly in aqueous formulations, which affect product stability and skin safety.

Innovation Solution

Development of ultraviolet-shielding composite particles incorporating metal oxide particles and organic ultraviolet absorbents within a resin matrix, produced through suspension or emulsion polymerization, allowing for their dispersion in both water-in-oil and oil-in-water cosmetic materials without the need for specific solvents, ensuring stability and reduced skin contact.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If inorganic ultraviolet-shielding agents and organic ultraviolet absorbents are jointly used, then the ultraviolet-shielding function is improved, but the organic ultraviolet absorbent recrystallizes due to metal ions causing alteration and discoloration

Engineering Contradiction:
Improveultraviolet-shielding functionVSAvoidcosmetic material stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent introduces an organic solvent as an intermediary substance that mediates between the inorganic ultraviolet-shielding agent and the organic ultraviolet absorbent. The organic solvent dissolves the organic ultraviolet absorbent and forms a complex with the inorganic ultraviolet-shielding agent, preventing direct harmful interactions while maintaining the ultraviolet-shielding function. This resolves the contradiction by using the organic solvent as a buffer that prevents recrystallization and discoloration.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent creates a composite system consisting of inorganic ultraviolet-shielding agent, organic ultraviolet absorbent, and organic solvent working together. The composite structure allows the inorganic agent to provide broad-spectrum shielding while the organic absorbent enhances specific wavelength protection, and the organic solvent maintains stability by preventing recrystallization. This composite approach enables both agents to function synergistically without the harmful effects of direct contact.

Inventive Principle:
Principle #40Composite materials

2Reliability

If organic ultraviolet absorbent is used to provide ultraviolet-shielding function, then the shielding effect is improved, but the absorbent is insoluble in water requiring specific solvents which limits formulation flexibility

Engineering Contradiction:
Improveultraviolet-shielding functionVSAvoidformulation flexibility
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The organic solvent serves multiple functions simultaneously: it dissolves the water-insoluble organic ultraviolet absorbent, forms a complex with the inorganic ultraviolet-shielding agent to enhance stability, and acts as a bridge enabling the formulation to work in both aqueous and non-aqueous cosmetic products. This multi-functionality resolves the contradiction by making the organic absorbent compatible with water-based formulations while maintaining its shielding effectiveness.

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Reliability

If organic ultraviolet absorbent is used in cosmetic products, then the ultraviolet-shielding function is improved, but sensitive skin users experience allergic symptoms upon repetitive use

Engineering Contradiction:
Improveultraviolet-shielding functionVSAvoidskin allergic reaction
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The organic solvent acts as a protective intermediary between the organic ultraviolet absorbent and the skin. By forming a stable complex and preventing recrystallization, the solvent reduces the likelihood of the absorbent precipitating onto the skin, thereby minimizing direct contact and potential allergic reactions in sensitive users while maintaining the shielding function.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composite particles provide enhanced stability and safety by preventing recrystallization and discoloration, enabling broader formulation flexibility and maintaining transparency, while ensuring effective ultraviolet shielding without adverse skin reactions.

Implementation Method 1

metal oxide particles having an ultraviolet-shielding function

Methodology Applied
Scientific EffectUltraviolet shielding: Absorption (EM radiation)

Implementation Method 2

metal oxide particles...provide ultraviolet-shielding function

Methodology Applied
Scientific EffectLight scattering: Scattering

Implementation Method 3

organic ultraviolet absorbent...wavelengths of ultraviolet rays, which can be shielded by inorganic ultraviolet-shielding agents and organic ultraviolet absorbents

Methodology Applied
Scientific EffectUltraviolet absorption: Absorption (EM radiation)

Implementation Method 4

resin monomers are polymerized through suspension polymerization or emulsion polymerization

Methodology Applied
Scientific EffectPolymerization: Photopolymerisation

Data Source

PatentUS9168208B2Ultraviolet-shielding composite particles, method for manufacturing the same, ultraviolet-shielding composite particle-containing dispersion liquid, aqueous dispersion element, oil-based dispersion element and cosmetic material
Publication Date: 2015.10.27 SUMITOMO OSAKA CEMENT CO LTD
  • US9168208B2 patent drawing
  • US9168208B2 patent drawing
  • US9168208B2 patent drawing

AI summary

Ultraviolet-shielding composite particles of the invention are ultraviolet-shielding composite particles which include a resin containing an organic ultraviolet absorbent and metal oxide particles having an ultraviolet-shielding function, and have an average particle diameter of 0.05 μm or more and 5 μm or less, in which the metal oxide particles are particles which include one or two or more selected from the group consisting of zinc oxide, titanium oxide, cerium oxide and iron oxide and have an average particle diameter of 0.003 μm or more and 0.1 μm or less, a content of the organic ultraviolet absorbent in the ultraviolet-shielding composite particles is 0.1% by mass or more 80% by mass or less, a content of the metal oxide particles is 1% by mass or more 80% by mass or less, and the metal oxide particles are dispersed in the ultraviolet-shielding composite particles.