Vacuum Deposition Sonic Jet for Stable Zn-Mg Alloy Coatings

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Solution Overview

Problem

Existing methods for vacuum deposition of metal alloy coatings on substrates face challenges such as instability in coating composition over long lengths, complexity and cost of diffusion heat treatment, and difficulty in achieving constant layer thickness, particularly for materials like bake-hardening steel strips.

Innovation Solution

A process and installation for vacuum deposition using a sonic jet of metallic vapor from a bath with a controlled composition of zinc and magnesium, ensuring constant vapor flux and composition during deposition, which allows for continuous coating of substrates with a metal alloy layer of predetermined magnesium content.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If successive deposition of elements followed by diffusion heat treatment is used, then alloyed coating can be obtained, but the process becomes complex and expensive due to large quantities of inerting gas required

Engineering Contradiction:
Improvecoating compositionVSAvoidheat treatment process
Core Design Contradiction:
Stability of the object's compositionVSDevice complexity

Solution Approach 1:

The invention divides the coating process into two separate vacuum deposition chambers: a first chamber for depositing the base metal layer and a second chamber for depositing the alloying element layer. This segmentation eliminates the need for complex diffusion heat treatment and large quantities of inerting gas, while still achieving stable alloyed coating composition through controlled sequential deposition.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention introduces a transfer mechanism (such as a transfer roller or belt) as an intermediary between the two vacuum deposition chambers. This intermediary allows the substrate to move from the first chamber to the second chamber without exposure to atmospheric conditions, enabling continuous process operation without complex heat treatment steps.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Object-affected harmful factors

If diffusion heat treatment is performed immediately after magnesium deposition, then oxidation is prevented, but the process requires continuous operation without air exposure

Engineering Contradiction:
Improveoxidation preventionVSAvoidcontinuous operation requirement
Core Design Contradiction:
Object-affected harmful factorsVSProductivity

Solution Approach 1:

The invention segments the deposition process into distinct stages in separate vacuum chambers, allowing each chamber to be optimized for its specific function. The first chamber handles base metal deposition, while the second chamber handles alloying element deposition, enabling independent process control and eliminating the need for immediate continuous operation.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention maintains continuous vacuum protection throughout the transfer and deposition process, ensuring that the substrate remains protected from oxidation without requiring immediate heat treatment. The continuous vacuum environment allows for flexible production scheduling while preventing harmful oxidation.

Inventive Principle:
Principle #20Continuity of useful action

3Stability of the object's composition

If precise control of layer thickness is maintained, then constant coating composition is achieved, but the process becomes difficult to control over long substrate lengths

Engineering Contradiction:
Improvecoating composition constancyVSAvoidprocess control
Core Design Contradiction:
Stability of the object's compositionVSEase of operation

Solution Approach 1:

The invention incorporates feedback control mechanisms for the vapor flux from the alloying element source, using sensors to monitor deposition rate and composition in real-time. This feedback system automatically adjusts deposition parameters to maintain constant coating composition over long substrate lengths, simplifying process control while ensuring composition stability.

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The invention controls coating composition by adjusting vapor flux parameters (such as source temperature, deposition rate, and chamber pressure) rather than relying solely on physical layer thickness control. This parameter-based control method provides more flexible and easier control of coating composition over varying substrate lengths.

Inventive Principle:
Principle #35Parameter changes

4Quantity of substance

If high evaporation temperatures are used for both zinc and magnesium, then sufficient vapor flux is obtained, but the temperature difference between elements complicates the process

Engineering Contradiction:
Improvevapor fluxVSAvoidevaporation temperature difference
Core Design Contradiction:
Quantity of substanceVSTemperature

Solution Approach 1:

The invention separates the evaporation processes for base metal and alloying elements into different vacuum chambers, allowing each chamber to be optimized for its specific temperature requirements. This segmentation enables independent temperature control for each element source, simplifying the process despite the temperature difference between zinc and magnesium.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention adjusts evaporation temperature as a controllable parameter for each element source independently. By optimizing the temperature parameter for each chamber based on the specific element being deposited, sufficient vapor flux is achieved for both zinc and magnesium without being constrained by their temperature difference.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables simple industrial implementation of stable and uniform metal alloy coatings on varied substrates, avoiding the complexities of diffusion heat treatment and ensuring compatibility with different metallurgies, while maintaining high corrosion resistance and material yield.

Implementation Method 1

a vapor obtained by evaporation of a metal bath based on zinc and initially comprising a predetermined proportion of magnesium

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 2

a process for continuously coating a substrate and an installation for the vacuum deposition of coatings formed from metal alloys

Methodology Applied
Scientific EffectVacuum evaporation: Physical Vapour Deposition

Data Source

PatentEP2129810B1Method for coating a substrate and metal alloy vacuum deposition facility
Publication Date: 2016.07.20 ARCELORMITTAL SA
  • EP2129810B1 patent drawingFigure 1~2
  • EP2129810B1 patent drawingFigure 3
  • EP2129810B1 patent drawingFigure 4

AI summary

The invention relates to a method for coating a substrate (S) by continuously depositing on said substrate (S) a layer of a metal alloy including at least two metallic elements using a vacuum deposition facility (1) that comprises a vapour jet coating device (7) for spraying the substrate (S) with a vapour containing the metallic elements in a predetermined and constant relative proportion, wherein the vapour is previously accelerated to a sonic speed. The method is particularly intended for depositing Zn-Mg coatings. The invention also relates to a continuous metal alloy vacuum deposition facility (1) for implementing said method.