Multilayer Vacuum Skin Film for Humidity-Resistant Oxygen Barrier

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Solution Overview

Problem

Existing vacuum skin packaging (VSP) films face challenges in maintaining effective oxygen barrier properties under high humidity conditions due to the sensitivity of ethylene vinyl alcohol (EVOH) layers, requiring thick layers that increase polymer use and cost, while also needing to be formable and ovenable/microwavable.

Innovation Solution

Incorporating a layer of high moisture barrier polymer, such as HDPE, between the sealant and EVOH gas barrier in a multilayer film structure to reduce EVOH thickness and enhance oxygen barrier properties, with an asymmetrical layer configuration to prevent moisture from reaching the EVOH layer.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a thick EVOH barrier layer is used to maintain oxygen barrier properties under high humidity conditions, then the oxygen barrier performance is improved, but the polymer usage and cost increase

Engineering Contradiction:
Improveoxygen barrier performanceVSAvoidpolymer usage
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

A moisture barrier layer (such as HDPE, PP, or COC) is introduced as an intermediary between the sealant layer and the EVOH barrier layer. This intermediate layer blocks moisture from reaching the EVOH layer, preventing humidity-induced degradation of oxygen barrier properties. As a result, thinner EVOH layers (reducing polymer usage) can maintain effective oxygen barrier performance even in high humidity environments.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The packaging film is designed as a composite multilayer structure combining different materials with complementary functions: a sealant layer for sealing, a moisture barrier layer (HDPE/PP/COC) to block moisture, and an EVOH layer for oxygen barrier. This composite structure allows each layer to perform its specific function optimally, enabling reduced EVOH thickness while maintaining overall barrier performance.

Inventive Principle:
Principle #40Composite materials

2Reliability

If a thick EVOH barrier layer is used to ensure oxygen barrier properties under high humidity conditions, then the oxygen barrier performance is improved, but the manufacturing cost increases

Engineering Contradiction:
Improveoxygen barrier performanceVSAvoidmanufacturing cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The moisture barrier layer (HDPE, PP, or COC) serves as a protective intermediary that shields the EVOH layer from moisture exposure. This allows the EVOH layer to be thinner and less expensive while still maintaining effective oxygen barrier properties, thereby reducing manufacturing costs without compromising barrier performance.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The multilayer composite structure distributes the barrier functions across different materials, allowing the EVOH layer to be optimized for oxygen barrier at reduced thickness. The moisture barrier layer handles moisture protection, enabling cost-effective manufacturing by reducing the quantity and cost of EVOH material required.

Inventive Principle:
Principle #40Composite materials

3Quantity of substance

If the EVOH layer is made thinner to reduce polymer usage, then the oxygen barrier performance may be maintained, but the layer becomes more sensitive to humidity effects

Engineering Contradiction:
ImproveEVOH thicknessVSAvoidresistance to humidity effects
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The moisture barrier layer (HDPE, PP, or COC) acts as a protective intermediary that prevents humidity from reaching the thinner EVOH layer. This intermediary layer decouples the EVOH layer from humidity exposure, allowing the EVOH to be made thinner without compromising its resistance to humidity effects or maintaining effective oxygen barrier performance.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The film achieves improved oxygen barrier performance with reduced EVOH thickness, extending shelf life of packaged products and maintaining effectiveness under varying humidity conditions, while being formable and suitable for oven or microwave use.

Implementation Method 1

Incorporating a layer of high moisture barrier polymer, such as HDPE, between the sealant and EVOH gas barrier in a multilayer film structure to reduce EVOH thickness and enhance oxygen barrier properties

Methodology Applied
Scientific EffectMoisture barrier: Permeation

Implementation Method 2

The film achieves improved oxygen barrier performance with reduced EVOH thickness, extending shelf life of packaged products

Methodology Applied
Scientific EffectGas barrier: Permeation

Data Source

PatentUS20250326211A1Multilayer film for vacuum skin packaging, method of packaging and packages obtained therewith
Publication Date: 2025.10.23 CRYOVAC INC

AI summary

The present invention relates to packaging films, more specifically to packaging films useful in vacuum skin packaging applications characterized by excellent oxygen barrier properties, to a method of packaging by using said films and to packages obtained therewith.