Vanadium Electrolyte Production Using NH4VO3 Self-Reduction Roasting
Find Innovative SolutionsGenerate Solutions
Solution Overview
Problem
Conventional methods for manufacturing vanadium electrolyte use expensive vanadium oxide (V2O5) as a raw material and additional reducing agents, leading to high costs and impurity issues.
Innovation Solution
A method utilizing ammonium trioxovanadate (NH4VO3) as a cheaper raw material, undergoing reduction roasting at specific temperatures and times to form vanadium (IV) oxide (V2O4) and/or vanadium (III) oxide (V2O3), which are then dissolved in sulfuric acid to produce the electrolyte without additional reducing agents.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Manufacturing precision
If vanadium (V) oxide (V2O5) is used as the raw material, then the vanadium electrolyte can be manufactured, but the manufacturing cost is high
Solution Approach 1:
The patent substitutes expensive vanadium (V) oxide with cheaper vanadium (IV) oxide and/or vanadium (III) oxide as raw materials. These cheaper vanadium compounds achieve the same electrolyte manufacturing purpose without the high cost burden, directly resolving the contradiction between electrolyte quality and manufacturing cost.
Solution Approach 2:
The patent changes the oxidation state parameter of the vanadium compound from +5 (V2O5) to +4 (V2O4) and/or +3 (V2O3). This parameter change in the raw material's chemical state enables cost reduction while maintaining the ability to produce functional vanadium electrolyte.
2Manufacturing precision
If additional reducing agents are added, then the vanadium electrolyte can be formed, but impurity problems occur
Solution Approach 1:
The patent utilizes the ammonia gas generated during the heating process of ammonium metavanadate as the reducing agent. This self-generated reducing agent eliminates the need for external reducing agents, thereby avoiding the introduction of additional impurities and simplifying the manufacturing process.
Solution Approach 2:
The patent uses ammonia gas as an intermediary substance that serves dual purposes: it is a byproduct of heating ammonium metavanadate and simultaneously functions as the reducing agent. This intermediary approach avoids direct addition of external reducing agents that would introduce impurities.
3Manufacturing precision
If additional reducing agents are added, then the vanadium electrolyte can be manufactured, but the manufacturing cost increases
Solution Approach 1:
The patent employs the ammonia gas generated from heating ammonium metavanadate as the reducing agent. This self-service approach eliminates the need to purchase and add external reducing agents, thereby reducing manufacturing costs while still achieving complete electrolyte formation.
Solution Approach 2:
The patent converts the ammonia gas, which could be considered a byproduct or waste, into a useful reducing agent. This transformation turns a potential waste stream into a valuable functional component, reducing the need for additional chemical additives and associated costs.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
Reduces manufacturing costs and avoids impurities, improving the quality and efficiency of the vanadium electrolyte by using ammonium trioxovanadate (NH4VO3) and optimizing roasting and dissolution parameters.
Implementation Method 1
carrying out a reduction roasting reaction of ammonium trioxovanadate (V) (NH4VO3) at a temperature of from 700° C. to 900° C. for a time period of 1 hour to 4 hours
Implementation Method 2
heating ammonium trioxovanadate (V) (NH4VO3) can be reduced by ammonia gas (NH3(g)) formed by heating ammonium trioxovanadate (V) (NH4VO3)
Implementation Method 3
dissolving the vanadium-containing mixture in an aqueous sulfuric acid solution to obtain the vanadium electrolyte
Data Source
AI summary
A method for manufacturing a vanadium electrolyte is used to solve the problem that the expansive raw material and the additional reducing agent are used in the conventional method. The method comprises: preforming a reduction roasting reaction of ammonium trioxovanadate (V) (NH4VO3) at a temperature of 700° C. to 900° C. for a time period of 1 hour to 4 hours to obtain a first vanadium-containing mixture. The first vanadium-containing mixture is dissolved in a first aqueous sulfuric acid solution to obtain the vanadium electrolyte. Accordingly, the manufacturing cost of the vanadium electrolyte is reduced, and the quality of the vanadium electrolyte is improved.


