Vapor Space Anticorrosive Composition for Engine Residue Protection

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Solution Overview

Problem

Corrosion protection in hollow objects is inadequate, especially after the removal of liquid-based running-in compositions, as these objects are left exposed to air and can corrode due to residual liquid residues, leading to accelerated corrosion in vapor spaces within engines.

Innovation Solution

A vapor space anticorrosive composition comprising alkoxylated castor oil as a corrosion inhibitor and alkyl amine ethoxylates as surfactants, which provides effective corrosion protection even after the primary medium has been drained, suitable for use as an engine run-in composition or coolant, with a phase inversion temperature tailored for improved protection.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If liquid-based running-in compositions are used for engine corrosion protection, then corrosion protection is provided during operation, but after draining the liquid, residual residues remain that accelerate corrosion in vapor spaces

Engineering Contradiction:
Improvecorrosion protectionVSAvoidcorrosive atmosphere from residues
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The invention changes the physical-chemical parameters of the corrosion protection system by introducing a vapor-active corrosion inhibitor that operates in the vapor phase rather than liquid phase. The composition is designed to evaporate and form a protective vapor atmosphere, transforming the mode of action from liquid-based to vapor-based corrosion protection, thereby eliminating the problem of corrosive residues.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention extracts and isolates the corrosion protection function to operate independently in the vapor phase. By using volatile corrosion inhibitors that evaporate and protect surfaces in the vapor space, the system separates the protection mechanism from the liquid coolant, allowing the liquid to be drained while the vapor-phase protection remains effective.

Inventive Principle:
Principle #2Taking out (Extraction)

2Reliability

If conventional vapor space corrosion inhibitors are used, then some corrosion protection is provided, but the protection is insufficient and does not maintain efficacy after the primary medium is removed

Engineering Contradiction:
Improvecorrosion protection efficacyVSAvoidduration of protection after draining
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The invention applies preliminary action by having the corrosion inhibitor evaporate and establish a protective vapor atmosphere before the liquid is drained. The vapor-phase inhibitor is already in position and active when the liquid coolant is removed, ensuring continuous protection without interruption or loss of efficacy.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The invention ensures continuity of useful action by designing a system where the corrosion protection transitions smoothly from liquid phase to vapor phase. The volatile inhibitor maintains continuous protective action throughout the draining process and afterward, eliminating gaps in protection that occur with conventional liquid-based systems.

Inventive Principle:
Principle #20Continuity of useful action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition effectively inhibits corrosion in metal objects and others made of corrosion-prone materials by forming a protective layer that maintains efficacy even after the primary medium has been removed, significantly reducing corrosion in vapor spaces within engines and other hollow structures.

Implementation Method 1

The composition effectively inhibits corrosion in metal objects and others made of corrosion-prone materials by forming a protective layer

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

A vapor space anticorrosive composition comprising alkoxylated castor oil as a corrosion inhibitor and alkyl amine ethoxylates as surfactants

Methodology Applied
Scientific EffectSurfactant: Surfactant

Data Source

PatentEP2841622B1Novel vapor space anticorrosive composition
Publication Date: 2020.06.10 BASF SE
  • EP2841622B1 patent drawing

AI summary

The present invention refers to a vapor space anticorrosive composition comprising corrosion inhibitors, surfactants and possibly thickeners, wherein one surfactant is selected from alkylamine ethoxylates, and being useful as an engine run-in composition and as a coolant.