Variable Path Length Cell for Downhole Spectroscopy

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Solution Overview

Problem

Spectroscopic analysis in downhole environments faces challenges due to varying optical densities of oils over multiple orders of magnitude, limited path lengths, and reduced detector sensitivity at high temperatures, which complicates the application of the Beer-Lambert law and limits the dynamic range of detectors.

Innovation Solution

The use of an axisymmetric surface with a shape defined by x = −a * Log(r / b) for the optical path length, where x is the optical path length and r is the distance from the revolving axis, allows for a linear relationship between transmission and absorption coefficient, reducing the dynamic performance requirements of analyzers and extending the dynamic range of sample measurements.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Device complexity

If a fixed path length is used for spectroscopic analysis, then the measurement setup is simple, but the dynamic range is limited due to varying optical densities of oils over multiple orders of magnitude

Engineering Contradiction:
Improvemeasurement setup complexityVSAvoiddynamic range
Core Design Contradiction:
Device complexityVSAdaptability or versatility

Solution Approach 1:

The patent implements a variable path length cell where the optical path length can be dynamically adjusted to accommodate different optical densities of oil samples. The cell includes movable components that allow the path length to be changed during measurements, enabling the system to adapt to a wide dynamic range of absorption coefficients without requiring multiple fixed cells or complex sample preparation.

Inventive Principle:
Principle #15Dynamics

2Adaptability or versatility

If the path length is increased to measure higher optical densities, then the measurement range expands, but the detector sensitivity is reduced at high temperatures

Engineering Contradiction:
Improvemeasurement rangeVSAvoiddetector sensitivity
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent changes the physical parameter of path length dynamically to optimize the balance between measurement range and detector performance. By adjusting the path length based on the specific sample properties and measurement conditions, the system can maintain optimal detector sensitivity while expanding the measurable range. The variable path length cell allows real-time optimization of the light-sample interaction to compensate for temperature-induced detector sensitivity changes.

Inventive Principle:
Principle #35Parameter changes

3Device complexity

If a single fixed path length cell is used, then the device is simple, but it cannot accommodate oils with optical densities varying over multiple orders of magnitude

Engineering Contradiction:
Improvecell structureVSAvoidoptical density range
Core Design Contradiction:
Device complexityVSAdaptability or versatility

Solution Approach 1:

The patent employs a variable path length cell design that allows the optical path length to be dynamically adjusted within a single cell structure. This dynamic capability enables the cell to accommodate oil samples with optical densities varying over multiple orders of magnitude, eliminating the need for multiple fixed cells while maintaining measurement versatility across different concentration ranges.

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach transforms the exponential relationship between transmission and absorption into a linear one, significantly reducing the dynamic range demands on detectors and enabling measurements over a broader range of optical densities, thus improving the accuracy and reliability of spectroscopic analysis in challenging environments.

Implementation Method 1

According to the Beer-Lambert law, the intensity of light transmitted through a samples varies exponentially with respect to the absorptivity of the sample... the intensity of light transmitted through a samples varies exponentially with respect to the absorptivity of the sample (usually expressed as molar absorptivity or molecular absorptivity), the path length through which the light is transmitted, and the concentration of the absorbing species in the sample

Methodology Applied
Scientific EffectBeer-Lambert law: Absorption (EM radiation)

Data Source

PatentEP2449354B1Energy intensity transformation
Publication Date: 2020.06.03 HALLIBURTON ENERGY SERVICES INC
  • EP2449354B1 patent drawingFigure 1
  • EP2449354B1 patent drawingFigure 2
  • EP2449354B1 patent drawingFigure 3

AI summary

Apparatus, systems, and methods may operate to receive incident energy within a chamber defining a first part of an interaction volume that attenuates the incident energy as a function of path length to provide attenuated energy. Additional activity may include simultaneously transforming the attenuated energy characterized by a substantially exponential intensity function into resultant energy characterized by a substantially polynomial intensity function. The transformation may be accomplished using an interacted energy transformation element that defines a second part of the interaction volume, the transformation element operating to intercept the attenuated energy along a plurality of path lengths. Other activity may include transmitting the resultant energy to a receiver. Additional apparatus, systems, and methods are disclosed.