Variable Resistance Element Sidewall Blocking Layer

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Solution Overview

Problem

Existing memory devices face challenges in preventing damage to variable resistance elements during the formation of passivation layers, particularly due to nitrogen and oxygen gases, which can lead to deterioration and performance degradation.

Innovation Solution

The implementation of a blocking layer substantially free of nitrogen and oxygen on the sidewalls of the variable resistance element, which prevents the diffusion of damaging gases such as N2, O2, and H2O during subsequent processes, thereby protecting the element and enhancing its performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a passivation layer is formed using conventional methods, then the variable resistance element is protected, but nitrogen and oxygen gases cause damage and deterioration to the element

Engineering Contradiction:
Improveintegrity of variable resistance elementVSAvoiddamage from nitrogen and oxygen gases
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

A blocking layer comprising a nitrogen-free layer and/or an oxygen-free layer is introduced as an intermediary between the variable resistance element and the passivation layer. This blocking layer prevents nitrogen and oxygen gases from the passivation layer from diffusing into and damaging the variable resistance element, thereby protecting the element while still allowing the passivation layer to provide its protective function.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The blocking layer creates an inert environment around the variable resistance element by using materials that are substantially free of nitrogen and oxygen. This inert atmosphere prevents harmful gas diffusion from the passivation layer to the sensitive variable resistance element, solving the contradiction between protection and gas damage.

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

2Reliability

If blocking layer is added to prevent gas diffusion, then element protection is improved, but device structure becomes more complex

Engineering Contradiction:
Improveprotection from gas diffusionVSAvoidstructure of memory device
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The blocking layer is segmented into functional sub-layers: a nitrogen-free layer and an oxygen-free layer. This segmentation allows each sub-layer to address specific gas diffusion issues independently, providing targeted protection while maintaining a manageable structural complexity.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The blocking layer is applied locally only where needed - specifically on the sidewalls of the variable resistance element - rather than uniformly across the entire device. This localized application provides precise protection against gas diffusion while minimizing the overall structural complexity and material usage.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This solution effectively prevents damage to the variable resistance element, ensuring stable and improved performance by blocking harmful gases and maintaining the integrity of the passivation layer, thus enhancing the reliability and efficiency of the memory device.

Implementation Method 1

a blocking layer disposed on at least sidewalls of the variable resistance element, wherein the blocking layer may include a layer that is substantially free of nitrogen, oxygen or a combination thereof

Methodology Applied
Scientific EffectDiffusion barrier: Diffusion Barrier

Data Source

PatentUS11706997B2Electronic device and method for fabricating the same
Publication Date: 2023.07.18 SK HYNIX INC
  • US11706997B2 patent drawing
  • US11706997B2 patent drawing
  • US11706997B2 patent drawing

AI summary

An electronic device may include a semiconductor memory, and the semiconductor memory may include a substrate; a variable resistance element formed over the substrate and exhibiting different resistance values representing different digital information, the variable resistance element including a free layer having a variable magnetization direction, a pinned layer having a fixed magnetization direction and a tunnel barrier layer interposed between the free layer and the pinned layer; and a blocking layer disposed on at least sidewalls of the variable resistance element, wherein the blocking layer may include a layer that is substantially free of nitrogen, oxygen or a combination thereof.