Variable Resistance Memory Cell With Segmented Tantalum Oxide Layers

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Solution Overview

Problem

The indeterminate mode of resistance change characteristics in variable resistance nonvolatile storage devices with oxygen-deficient tantalum oxide layers complicates transistor optimization and data management, leading to inefficient memory cell design and increased complexity in circuit configuration.

Innovation Solution

A 1T1R nonvolatile storage device with a variable resistance element featuring a first oxygen-deficient tantalum oxide layer with a lower oxygen content percentage and a second oxygen-deficient tantalum oxide layer with a higher oxygen content percentage, where the second layer is in contact with the upper electrode, allowing for unique determination of voltage application direction for resistance changes, optimizing transistor size and simplifying data management.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Device complexity

If a single oxygen-deficient tantalum oxide layer is used as the variable resistance layer, then the device structure is simple, but the mode of resistance change characteristics is indeterminate, complicating transistor optimization and data management

Engineering Contradiction:
Improvestructure simplicityVSAvoidtransistor optimization ease
Core Design Contradiction:
Device complexityVSEase of operation

Solution Approach 1:

The variable resistance layer is segmented into two distinct layers: a first oxygen-deficient tantalum oxide layer (TaOx where x<2.5) and a second oxygen-deficient tantalum oxide layer (TaOy where y<2.5 but y>x). This segmentation creates deterministic resistance change characteristics where the first layer controls SET operation and the second layer controls RESET operation, eliminating the mode indeterminacy present in single-layer structures.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Each layer is assigned different oxygen content percentages to provide localized functional properties. The first layer has lower oxygen content (higher oxygen deficiency) optimized for SET operation, while the second layer has higher oxygen content (lower oxygen deficiency) optimized for RESET operation. This local quality differentiation enables precise control over resistance transition characteristics.

Inventive Principle:
Principle #3Local quality

2Reliability

If transistor size is increased to accommodate indeterminate resistance change modes, then reliability improves, but integration density decreases

Engineering Contradiction:
Improveoperation stabilityVSAvoidtransistor area
Core Design Contradiction:
ReliabilityVSArea of moving object

Solution Approach 1:

The oxygen content percentage is used as a critical parameter to differentiate the two layers. By controlling the oxygen content to be lower in the first layer (TaOx) and higher in the second layer (TaOy), the patent establishes deterministic voltage thresholds for resistance transitions. This parameter control enables predictable SET and RESET operations, simplifying circuit configuration and data management.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces the mechanical approach of increasing transistor size to handle indeterminate modes with a material composition approach. By using oxygen content control in the layered structure, the system achieves reliable operation with smaller transistors, as the material properties themselves provide the determinism needed for stable resistance transitions.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables stable resistance changes with reduced substrate bias effect, allowing for smaller transistor design, increased integration density, and cost reduction by determining the voltage application direction for high and low resistance states, thus simplifying circuit management.

Implementation Method 1

a variable resistance layer which has a resistance value that reversibly changes based on voltage signals each of which has a different polarity and is applied between the first and second electrodes

Methodology Applied
Scientific EffectVariable resistance effect: Electrical Resistance

Implementation Method 2

the variable resistance layer includes: a first region which is in contact with the first electrode and contains a first oxygen-deficient transition metal oxide having a composition MOx; and a second region which is in contact with the second electrode and contains a second oxygen-deficient transition metal oxide having a composition MOy

Methodology Applied
Scientific EffectIon migration: Ion Repulsion/Attraction

Data Source

PatentUS8830730B2Variable resistance nonvolatile storage device and method of forming memory cell
Publication Date: 2014.09.09 PANASONIC SEMICON SOLUTIONS CO LTD
  • US8830730B2 patent drawing
  • US8830730B2 patent drawing
  • US8830730B2 patent drawing

AI summary

A variable resistance nonvolatile storage device which includes (i) a semiconductor substrate, (ii) a variable resistance element having: lower and upper electrodes; and a variable resistance layer whose resistance value reversibly varies based on voltage signals each of which has a different polarity and is applied between the electrodes, and (iii) a MOS transistor formed on the substrate, wherein the variable resistance layer includes: oxygen-deficient transition metal oxide layers having compositions MOx and MOy (where x&lt;y) and in contact with the electrodes respectively, a diffusion layer region is connected with the lower electrode to form a memory cell, the region serving as a drain upon application of a voltage signal which causes a resistance change to high resistance state in the variable resistance layer.