Variable Resistance Memory Oxygen Deficient Region

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Solution Overview

Problem

Variable resistance memory devices face challenges in operational stability due to difficulties in uniformly controlling the formation and breakdown of conductive filaments, leading to inconsistent resistance states and high power consumption.

Innovation Solution

A variable resistance memory device is designed with an oxide layer having a vertically extending oxygen deficient region, where the distribution density of oxygen vacancies is controlled through an oxidation-reduction reaction between layers of differing oxygen affinity, allowing for uniform oxygen vacancy distribution and stable resistance switching.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If an electroforming process is used to induce soft breakdown phenomenon in the insulator, then a conductive filament can be formed, but it is difficult to uniformly control the formation and breaking down of the CF, leading to deteriorated operational stability

Engineering Contradiction:
Improveoperational stabilityVSAvoiduniformity of conductive filament formation
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent introduces a seed layer between the bottom electrode and the insulator layer before forming the conductive filament. This seed layer pre-establishes a region with controlled oxygen vacancy distribution, which guides and uniformizes the subsequent electroforming process. The preliminary presence of the seed layer ensures that conductive filaments form consistently at the same location with uniform characteristics across different devices and operating cycles.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent modifies the physical and chemical parameters of the insulator layer by introducing a seed layer with specific oxygen vacancy concentration and distribution. This changes the local electrical properties, oxygen diffusion characteristics, and breakdown voltage distribution in the forming region. By controlling parameters such as seed layer thickness, material composition, and oxygen vacancy density, the uniformity of conductive filament formation is significantly improved while maintaining operational stability.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If high power is applied to induce soft breakdown, then conductive filament formation can be achieved, but power consumption increases and operational stability deteriorates

Engineering Contradiction:
Improveoperational stabilityVSAvoidpower consumption
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The seed layer is prepared in advance to create a region with optimized oxygen vacancy distribution and reduced breakdown strength. This preliminary preparation eliminates the need for high-power pulses during operation, as the electroforming process occurs at lower voltages due to the pre-conditioned seed layer region. The seed layer acts as a catalyst that reduces the energy barrier for conductive filament formation.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The seed layer serves as an intermediary between the bottom electrode and the insulator layer, mediating the electroforming process. It provides a controlled interface that facilitates oxygen vacancy generation and migration at lower applied voltages. The seed layer absorbs excess energy and directs it toward productive filament formation rather than random breakdown, thereby reducing overall power consumption while improving operational stability.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances operational stability and enables low-power, gradual resistance state switching, suitable for applications in neuromorphic devices and multi-bit level memory systems.

Implementation Method 1

forming an oxide layer including an oxygen deficient region through an oxidation-reduction reaction occurring at an interface between the first layer and the second layer

Methodology Applied
Scientific EffectOxidation-reduction reaction: Redox Reactions

Implementation Method 2

the memory cell having a varying resistance according to a distribution density of oxygen vacancies in the memory cell

Methodology Applied
Scientific EffectElectrical resistance change: Electrical Resistance

Data Source

PatentUS11563172B2Variable resistance memory device and manufacturing method of the same
Publication Date: 2023.01.24 SK HYNIX INC
  • US11563172B2 patent drawing
  • US11563172B2 patent drawing
  • US11563172B2 patent drawing

AI summary

There are provided a variable resistance memory device and a manufacturing method of the same. The variable resistance memory device includes: a first electrode; a second electrode arranged in a vertical direction from the first electrode; and an oxide layer having an oxygen deficient region extending in the vertical direction between the second electrode and the first electrode.