Vegetable Black Ink Dispersion via Metal Ion Complexation

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Ink jet inks using vegetable black-derived colorants face challenges with high sedimentation properties due to large particle diameters, leading to degradation in ejection stability and storage stability.

Innovation Solution

A water-based ink jet ink composition containing a vegetable black-derived colorant, a lignosulfonate salt, and specific metal elements (Ca, Mg, Mn, Fe, Al, Si, Cr, Ni, Sr, and Ba) at concentrations of 50 to 1,700 mass ppm, which improves dispersion stability and storage stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If vegetable black-derived colorant is used in ink jet ink, then natural safety and environmental friendliness are improved, but sedimentation rate increases due to large particle diameter

Engineering Contradiction:
Improvenatural safetyVSAvoidsedimentation rate
Core Design Contradiction:
Object-affected harmful factorsVSStability of the object's composition

Solution Approach 1:

The patent introduces metal elements (Ca, Mg, Mn, Fe, Al, Si, Cr, Ni, Sr, or Ba) as intermediary substances that interact with vegetable black particles. These metal elements form complexes with the vegetable black, reducing particle aggregation and improving dispersion stability, thereby suppressing sedimentation while maintaining the natural safety of the ink composition.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the chemical composition parameters of the ink by adding specific metal elements at controlled concentrations (50 to 1,700 mass ppm). This parameter change modifies the interaction between ink components and vegetable black particles, improving ejection stability and reducing sedimentation rate while preserving the natural characteristics of the ink.

Inventive Principle:
Principle #35Parameter changes

2Object-affected harmful factors

If vegetable black-derived colorant with large particle diameter is used, then natural safety is improved, but ejection stability degrades

Engineering Contradiction:
Improvenatural safetyVSAvoidejection stability
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

Metal elements serve as intermediary substances that form stable complexes with vegetable black particles. This complexation prevents particle aggregation and ensures uniform ink ejection, thereby improving ejection stability while maintaining the natural safety benefits of vegetable black-derived colorants.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

By adjusting the concentration of metal elements (50 to 1,700 mass ppm) in the ink composition, the patent optimizes the interaction between ink components and vegetable black particles. This parameter optimization ensures stable ink ejection performance while preserving the natural safety characteristics.

Inventive Principle:
Principle #35Parameter changes

3Object-affected harmful factors

If vegetable black-derived colorant is used, then environmental friendliness is improved, but storage stability decreases

Engineering Contradiction:
Improveenvironmental friendlinessVSAvoidstorage stability
Core Design Contradiction:
Object-affected harmful factorsVSStability of the object's composition

Solution Approach 1:

Metal elements act as intermediary substances that form stable complexes with vegetable black particles during storage. This complexation prevents particle aggregation and sedimentation, thereby improving storage stability while maintaining the environmental friendliness of the natural-based ink composition.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent optimizes the concentration of metal elements (50 to 1,700 mass ppm) to achieve optimal storage stability. This parameter control ensures that the ink maintains its performance characteristics over time while preserving the environmental benefits of using naturally-derived colorants.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ink composition achieves enhanced storage stability and printing stability, with improved ejection stability and reduced sedimentation rates, allowing for stable recording even with repetitive printing.

Implementation Method 1

a water-based ink jet ink composition which contains a vegetable black-derived colorant, a lignosulfonate salt, and an element A which includes at least one selected from the group consisting of Ca, Mg, Mn, Fe, Al, Si, Cr, Ni, Sr, and Ba

Methodology Applied
Scientific EffectDispersion: Dispersion (of waves)

Implementation Method 2

an ink composition using a vegetable black has a high sedimentation property because of its large particle diameter

Methodology Applied
Scientific EffectSedimentation: Sedimentation

Implementation Method 3

a lignosulfonate salt

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS12312485B2Ink jet ink composition, recording method, and recorded matter
Publication Date: 2025.05.27 SEIKO EPSON CORP
  • US12312485B2 patent drawing

AI summary

An ink jet ink composition is a water-based ink jet ink composition and includes a vegetable black-derived colorant, a lignosulfonate salt, and an element A which includes at least one selected from the group consisting of Ca, Mg, Mn, Fe, Al, Si, Cr, Ni, Sr, and Ba, and a content of the element A with respect to a total mass of the ink composition is 50 to 1,700 mass ppm.