Vegetable Oil Extended SSBR for Tire Traction

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Solution Overview

Problem

Tire tread rubber compositions face challenges in achieving high traction and durability while maintaining flexibility at lower temperatures, as existing high glass transition temperature (Tg) styrene/butadiene rubber (SSBR) compositions tend to be stiff, affecting wet traction performance.

Innovation Solution

A rubber composition is developed using a high Tg SSBR extended with vegetable triglyceride oil instead of petroleum-based oil, combined with precipitated silica and a traction-promoting resin, to reduce the rubber's glass transition temperature and enhance traction and durability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If high Tg SSBR is used to promote wet traction, then traction performance is improved, but the rubber composition becomes stiff at lower temperatures

Engineering Contradiction:
Improvewet tractionVSAvoidflexibility at lower temperatures
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The patent changes the chemical composition parameters by incorporating vegetable oil extended high Tg SSBR with specific Tg range (-20°C to +10°C), bound styrene content (25-50%), and vinyl 1,2-content (10-80%). It also optimizes the silica content (50-100 phr) and silica coupler (2-10 phr) to achieve the right balance between traction and flexibility. These parameter adjustments allow the rubber composition to maintain high wet traction while improving low-temperature flexibility.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite rubber composition by combining multiple materials: vegetable oil extended high Tg SSBR, precipitated silica, silica coupler, and optionally carbon black. This composite approach allows the synergistic interaction between components to achieve both high traction performance and improved low-temperature flexibility that cannot be obtained with single materials alone.

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If petroleum-based oil is used to extend SSBR, then processing is simplified, but environmental sustainability is reduced

Engineering Contradiction:
Improveprocessing simplicityVSAvoidenvironmental sustainability
Core Design Contradiction:
Ease of manufactureVSObject-affected harmful factors

Solution Approach 1:

The patent replaces petroleum-based processing oil with vegetable oil (such as soybean oil, canola oil, or sunflower oil) as an environmentally friendly alternative. This substitution maintains the extending function while reducing environmental harm, as vegetable oils are renewable and biodegradable resources.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent converts the potential disadvantage of using vegetable oil (higher cost or different processing characteristics) into a benefit by demonstrating that vegetable oil extension provides both environmental sustainability and effective rubber compounding performance, thereby turning an alternative into a superior solution.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves improved wet traction and durability by maintaining flexibility at lower temperatures, balancing performance at both high and low ambient temperatures, thereby enhancing the tire's grip and rolling resistance.

Implementation Method 1

it is also desired to reduce the Tg of the rubber composition to promote the tread traction at lower temperatures by thereby reducing its stiffness

Methodology Applied
Scientific EffectGlass transition:

Implementation Method 2

The reinforcing filler also contains a silica coupler (silica coupling agent) for the silica

Methodology Applied
Scientific EffectSilica coupling:

Implementation Method 3

The tire tread is provided as a sulfur cured rubber composition

Methodology Applied
Scientific EffectVulcanization:

Data Source

PatentEP3513988B1Rubber composition and tire with tread containing vegetable oil extended high tg styrene/butadiene elastomer and traction resin
Publication Date: 2020.12.09 THE GOODYEAR TIRE & RUBBER CO

AI summary

A rubber composition for use in a pneumatic tire, preferably in a tread of such a tire is disclosed. The rubber composition comprises, based on parts by weight per 100 parts by weight elastomer (phr): (A) one or more conjugated diene-based elastomers comprising: (1) from 75 to 100 phr of at least one styrene/butadiene elastomer (SSBR) pre-extended with a vegetable triglyceride oil, wherein said at least one SSBR has a Tg in a range of from -20°C to +10°C and a bound styrene content in a range of from 25 to 50 percent, (2) from zero to 25 phr of at least one additional conjugated diene-based elastomer comprising at least one of polybutadiene, cis 1,4-polyisoprene rubber and a further styrene/butadiene elastomer different from said at least one SSBR; (B) from 80 to 200 phr of a reinforcing filler; and (C) from 10 to 70 phr of a resin comprising at least one of styrene/alphamethylstyrene copolymer resin, terpene-phenol resin, coumarone-indene resin, petroleum hydrocarbon resin, terpene polymer resin, rosin derived resin, rosin acid resin, and modified rosin acid resin.