Two-Stage Venturi CO2 Removal with pH Segmentation

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Solution Overview

Problem

There is a need for an efficient and effective system to remove carbon dioxide from gas streams in various industrial and environmental sources, as carbon dioxide is a greenhouse gas contributing to global warming and climate change.

Innovation Solution

A system utilizing a series of venturi educators and reactors with alkaline solutions at specific pH ranges to induce reactions that convert carbon dioxide into metal bicarbonate and metal carbonate, with pH adjustment and dilution subsystems to prevent precipitation and maintain reaction efficiency, coupled with heat exchangers and evaporators for temperature control and waste heat utilization.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Device complexity

If a single-stage alkaline absorption system is used, then the system complexity is reduced, but the carbon dioxide removal efficiency is insufficient

Engineering Contradiction:
Improvesystem complexityVSAvoidcarbon dioxide removal efficiency
Core Design Contradiction:
Device complexityVSProductivity

Solution Approach 1:

The absorption system is divided into two distinct stages: a first absorption reactor operating at high pH (10-15) to remove the majority of CO2, and a second absorption reactor operating at lower pH (8-10) to polish remaining CO2. This segmentation allows each stage to be optimized for its specific function, achieving high overall removal efficiency while keeping individual reactor designs relatively simple

Inventive Principle:
Principle #1Segmentation

2Productivity

If alkaline solution concentration is increased to improve reaction rate, then carbon dioxide absorption speed increases, but metal carbonate precipitate formation increases

Engineering Contradiction:
Improvecarbon dioxide absorption speedVSAvoidmetal carbonate precipitate formation
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The system separates the high-concentration absorption function (first reactor with concentrated alkaline solution at pH 10-15) from the low-concentration polishing function (second reactor with diluted solution at pH 8-10). This segmentation allows the first reactor to operate at high concentration for fast reaction without excessive precipitate, while the second reactor handles remaining CO2 at lower concentration where precipitate formation is minimized

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The system dynamically adjusts pH as a critical parameter across different stages. The first reactor maintains pH 10-15 for rapid CO2 absorption, then the solution is diluted and pH is reduced to 8-10 in the second reactor. This parameter change optimizes both absorption speed and precipitate control at different stages of the process

Inventive Principle:
Principle #35Parameter changes

3Reliability

If continuous operation is maintained to ensure consistent carbon dioxide removal, then emission reduction is sustained, but alkaline solution consumption increases

Engineering Contradiction:
Improveconsistent carbon dioxide removalVSAvoidalkaline solution consumption
Core Design Contradiction:
ReliabilityVSLoss of substance

Solution Approach 1:

The system discards the depleted alkaline solution from the first reactor after it has absorbed the bulk of CO2, and recovers by introducing fresh alkaline solution. The second reactor similarly processes and discards its solution after polishing remaining CO2. This approach ensures continuous effective operation while managing alkaline solution consumption through controlled replacement rather than attempting full recycling

Inventive Principle:
Principle #34Discarding and recovering

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system effectively removes a majority of carbon dioxide from gas streams, reducing greenhouse gas emissions and minimizing operational costs by recycling alkaline solutions and utilizing waste heat, producing valuable metal bicarbonate or carbonate products.

Implementation Method 1

The first venturi eductor is configured to receive the flow of gas having carbon dioxide therein and a flow of a first alkaline solution

Methodology Applied
Scientific EffectVenturi Effect: Venturi Effect

Implementation Method 2

induce a reaction of the carbon dioxide with the first alkaline solution to form a solution having metal bicarbonate therein

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Implementation Method 3

at least one heat exchanger subsystem configured to cool the flow of the gas having carbon dioxide therein

Methodology Applied
Scientific EffectHeat exchange: Heat Exchanger

Data Source

PatentUS20240293774A1System and method for removing carbon dioxide from a flow of gas having carbon dioxide therein
Publication Date: 2024.09.05 ONTERRIS TREATMENT TECHNOLOGIES INC
  • US20240293774A1 patent drawing
  • US20240293774A1 patent drawing
  • US20240293774A1 patent drawing

AI summary

A system for removing carbon dioxide from a flow of gas having carbon dioxide therein is featured. The system includes a first venturi eductor and first reactor which receive the flow of gas having carbon dioxide therein and a flow of a first alkaline solution at a first predetermined pH range. The first venturi eductor and reactor mix and provide reaction time for the flow of gas having carbon dioxide therein and the flow of the first alkaline solution to induce a reaction of the carbon dioxide with the first alkaline solution to form a solution having metal bicarbonate therein. A second venturi eductor and reactor mix the flow of the partially treated gas with the flow of the second alkaline solution and provide reaction time to react a majority of the remaining carbon dioxide with the second alkaline solution to form a solution having metal carbonate therein.