Via Critical Dimension Control via Two-Step Silicon ARC Etch

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Solution Overview

Problem

The challenge in modern microstructure fabrication, such as integrated circuits, lies in achieving precise and reliable patterning of low-k dielectric materials for via openings and metal lines, particularly at deep sub-micron scales, due to the complexity of copper diffusion and the need for high aspect ratio filling, which results in significant process variability and increased reworking, affecting electrical performance and throughput.

Innovation Solution

Implementing a two-step etch process with controlled gas flow rates for patterning a silicon-containing ARC layer, allowing for efficient adaptation and adjustment of via opening dimensions, thereby reducing the spread of critical dimensions and increasing the valid range of lithography results, and using this layer as a mask for the hard mask material to enhance process control.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If a single-step etch process is used for patterning the ARC layer, then the process is simple and fast, but the critical dimension control is poor and reworking increases

Engineering Contradiction:
Improveetching speedVSAvoidcritical dimension control
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The etch process is divided into two distinct steps: a first etch step that etches a first portion of the ARC layer, and a second etch step that etches a second portion. This segmentation allows independent optimization of each step's parameters, enabling both high productivity and precise critical dimension control through selective gas flow rate adjustments in each step.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The etch process uses dynamic adjustment of gas flow rates between the two etching steps. By controlling the flow rate of the first gas component in the first step and the flow rate of the second gas component in the second step, the process adapts to achieve optimal etching profiles and critical dimensions, resolving the contradiction between speed and precision.

Inventive Principle:
Principle #15Dynamics

2Device complexity

If the lateral size of via openings is not controlled, then the lithography process is simple, but the spread of critical dimensions increases and electrical performance deteriorates

Engineering Contradiction:
Improvelithography process complexityVSAvoidspread of critical dimensions
Core Design Contradiction:
Device complexityVSManufacturing precision

Solution Approach 1:

The lateral size of the via openings is controlled during the etching of the ARC layer itself, rather than relying solely on lithography. By adjusting gas flow rates during the two-step etch process, the critical dimensions are predetermined and controlled at the etching stage, reducing the spread of critical dimensions without significantly increasing overall process complexity.

Inventive Principle:
Principle #10Preliminary action

3Reliability

If copper is used in the metallization system, then the electrical resistivity is reduced and electromigration resistance is improved, but copper diffusion in dielectric materials becomes a severe problem

Engineering Contradiction:
Improveelectrical performanceVSAvoidcopper diffusion
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

An anti-reflective coating (ARC) layer is introduced as an intermediary between the copper metallization and the underlying dielectric materials. This ARC layer serves as a diffusion barrier, preventing copper from diffusing into the dielectric while also providing optical properties for lithography. The two-step etch process selectively patterns this intermediary layer to control via opening dimensions.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach significantly reduces the spread of critical dimensions, decreases reworking, and enhances process robustness, allowing for a wider range of valid dimensions and improved electrical performance by efficiently controlling the lateral size of via openings, thus improving manufacturing efficiency and reducing maintenance needs.

Implementation Method 1

performing a first etch process by using an oxygen-containing precursor gas and a carbon and fluorine-containing precursor gas so as to form a first portion of an opening in a silicon-containing ARC layer

Methodology Applied
Scientific EffectPlasma etching: Plasma

Implementation Method 2

performing a first etch process by using an oxygen-containing precursor gas and a carbon and fluorine-containing precursor gas

Methodology Applied
Scientific EffectChemical vapor deposition: Chemical Vapour Deposition

Implementation Method 3

performing a second etch process by using a polymerizing precursor gas so as to form the opening in the silicon-containing ARC layer through the first portion

Methodology Applied
Scientific EffectPolymerization: Photopolymerisation

Data Source

PatentUS8492279B2Method of controlling critical dimensions of vias in a metallization system of a semiconductor device during silicon-ARC etch
Publication Date: 2013.07.23 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US8492279B2 patent drawing
  • US8492279B2 patent drawing
  • US8492279B2 patent drawing

AI summary

When forming via openings in sophisticated semiconductor devices, a silicon-containing anti-reflective coating (ARC) layer may be efficiently used for adjusting the critical dimension of the via openings by using a two-step etch process in which, in at least one of the process steps, the flow rate of a reactive gas component may be controlled to increase or reduce the resulting width of an opening in the silicon ARC layer. In this manner, the spread of critical dimensions of vias around the target value may be significantly reduced while also reducing any maintenance and rework efforts.