Via Cleaning via Nitrogen-Hydrogen Plasma for Semiconductor Interconnects

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Existing interconnect structures in semiconductor fabrication face issues with residue accumulation, leading to increased resistance and potential device failure due to metal oxide layer formation during etching processes, which blocks conductive paths and affects the integrity of the interconnect structure.

Innovation Solution

A plasma cleaning process using a nitrogen-hydrogen gas plasma is employed to remove metal oxide layers and residues formed during etching, ensuring clear conductive paths and reducing resistance by breaking and reducing these layers, thereby maintaining the critical dimensions and performance of the interconnect structure.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If etching processes are used to form interconnect structures, then conductive paths are created, but metal oxide layers and residues accumulate leading to increased resistance

Engineering Contradiction:
Improveconductive path formationVSAvoidelectrical connection reliability
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

A plasma cleaning process is performed before filling the via with conductive material to remove metal oxide layers and residues from the via walls. This preliminary cleaning action ensures that the conductive path will have low resistance and high reliability from the start, preventing connection issues before they occur.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The metal oxide layers and residues that accumulate during etching are converted from harmful contaminants into removable materials through plasma cleaning. The plasma process specifically targets and removes these oxides, transforming the problematic by-products of etching into easily eliminatable substances that do not interfere with subsequent conductive material deposition.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

2Reliability

If plasma cleaning is used to remove residues, then resistance is reduced, but process time and complexity increase

Engineering Contradiction:
Improveelectrical connection reliabilityVSAvoidfabrication process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

Plasma is introduced as an intermediary medium to facilitate the removal of metal oxide layers without requiring mechanical or chemical methods that would be more complex or damaging. The plasma acts as a controlled intermediary that selectively removes oxides while leaving the underlying structure intact, simplifying the overall cleaning process.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The plasma cleaning process effectively removes metal oxide residues and by-products, ensuring reliable electrical connections and reducing the resistance of the interconnect structure, thus enhancing the performance and reliability of semiconductor devices.

Implementation Method 1

A plasma cleaning process using a nitrogen-hydrogen gas plasma is employed to remove metal oxide layers and residues formed during etching

Methodology Applied
Scientific EffectPlasma: Plasma

Implementation Method 2

breaking and reducing these layers

Methodology Applied
Scientific EffectChemical reactions: Chemical Bonding

Data Source

PatentUS9761488B2Method for cleaning via of interconnect structure of semiconductor device structure
Publication Date: 2017.09.12 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US9761488B2 patent drawing
  • US9761488B2 patent drawing
  • US9761488B2 patent drawing

AI summary

A method for forming the semiconductor device structure is provided. The method includes forming a metal layer in a first dielectric layer over a substrate and forming an etch stop layer over the metal layer. The etch stop layer is made of metal-containing material. The method also includes forming a second dielectric layer over the etch stop layer and removing a portion of the second dielectric layer to expose the etch stop layer and to form a via by an etching process. The method further includes performing a plasma cleaning process on the via and the second dielectric layer, and the plasma cleaning process is performed by using a plasma including nitrogen gas (N2) and hydrogen gas (H2).