Viscoelastic Gel Delivery for High-Temperature Scale Removal

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Solution Overview

Problem

Conventional methods for delivering scale removal agents to high-temperature wells are ineffective due to the limitations of water-soluble agents and the highly viscous nature of oil-soluble agents, which restricts treatment effectiveness and accessibility in wells with bottomhole temperatures exceeding 300°F.

Innovation Solution

A delivery system utilizing a gelled fluid with a temperature-resistant viscoelastic surfactant, such as amine oxide, amidoamine oxide, or alkylamidoquaternary amine, that maintains stability at high temperatures and releases the scale removal agent upon degradation, allowing for controlled and deeper penetration into the well.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If water-soluble scale removal agents are used, then delivery is easier, but they are ineffective at high temperatures (above 300°F)

Engineering Contradiction:
Improvedelivery easeVSAvoideffectiveness at high temperature
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

A viscoelastic surfactant acts as an intermediary carrier that solubilizes scale removal agents in a gel structure, enabling delivery to high-temperature wells where conventional water-soluble agents fail. The surfactant forms a stable gel phase that protects the treatment agent until it reaches the target temperature zone.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The delivery system undergoes parameter changes by utilizing temperature-dependent phase transitions of the viscoelastic surfactant. The gel structure remains stable during delivery but transforms at high temperatures to release the scale removal agent, adapting its properties to the operating conditions.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If oil-soluble scale removal agents are used, then high temperature stability is improved, but viscosity becomes highly viscous restricting treatment effectiveness

Engineering Contradiction:
Improvehigh temperature stabilityVSAvoidtreatment accessibility
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The system uses parameter changes by exploiting the temperature-dependent rheological properties of the viscoelastic surfactant gel. The gel maintains appropriate viscosity for delivery at surface conditions but undergoes structural changes at high temperatures to enable effective treatment, avoiding the permanent high viscosity of oil-soluble agents.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The delivery system is a composite material combining viscoelastic surfactant, scale removal agent, and optional carrier fluids. This composite structure provides both the temperature stability of oil-soluble agents and the delivery characteristics of water-soluble systems, resolving the viscosity contradiction.

Inventive Principle:
Principle #40Composite materials

3Productivity

If mechanical devices are used for scale removal, then scale can be physically removed, but expensive well interventions are required

Engineering Contradiction:
Improvescale removal capabilityVSAvoidintervention cost
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The invention replaces mechanical scale removal devices (scrapers, reamers, wire lines) with a chemical treatment delivered via a viscoelastic gel system. The gel carries scale removal agents that chemically dissolve scales in place, eliminating the need for complex mechanical interventions and reducing operational costs.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

4Productivity

If downhole squeezing is used to deliver scale removal agent, then chemical treatment can be applied, but large volumes of fluid are required and it is limited to water-soluble agents

Engineering Contradiction:
Improvechemical treatment deliveryVSAvoidfluid volume required
Core Design Contradiction:
ProductivityVSQuantity of substance

Solution Approach 1:

The viscoelastic gel forms a concentrated composite material that incorporates scale removal agents in a compact structure. This eliminates the need for large volumes of dilute flush fluids required by conventional downhole squeezing methods, as the treatment agent is pre-concentrated in the gel matrix.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The viscoelastic surfactant acts as an intermediary that enables the delivery of scale removal agents in a compact gel form rather than requiring large volumes of carrier fluid. The surfactant structure allows high concentrations of treatment agent to be delivered efficiently to the wellbore.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system effectively delivers and releases scale removal agents at elevated temperatures, enhancing the removal of scales and improving well productivity by allowing deeper penetration and slower release of the agent, which is not achievable with traditional methods.

Implementation Method 1

a delivery system for introducing scale removal agents into a well having a bottomhole temperature in excess of 300° F., the delivery system being a gelled fluid of a temperature resistant viscoelastic surfactant and the scale removal agent

Methodology Applied
Scientific EffectGel formation: Gel

Implementation Method 2

The viscoelastic surfactant is an amine oxide, an amidoamine oxide or an alkylamidoquaternary amine

Methodology Applied
Scientific EffectViscoelasticity: Viscoelasticity

Implementation Method 3

Upon breakage of the bonds of the viscoelastic surfactant, the scale removal agent may be released from the gelled fluid

Methodology Applied
Scientific EffectThermal degradation: Thermolysis

Implementation Method 4

Upon breakage of the bonds of the viscoelastic surfactant, the scale removal agent may be released from the gelled fluid

Methodology Applied
Scientific EffectBond breakage: Chemical Bonding

Implementation Method 5

The delivery system provides a method for delivering a scale removal agent to a targeted area of a well or to a subterranean formation penetrated by a well at an elevated bottomhole temperature greater than or equal to 300° F.

Methodology Applied
Scientific EffectFluid flow: Convection

Data Source

PatentUS12168913B2Methods for transporting scale removal agents into a well
Publication Date: 2024.12.17 BAKER HUGHES HLDG
  • US12168913B2 patent drawing
  • US12168913B2 patent drawing
  • US12168913B2 patent drawing

AI summary

A scale removal agent may effectively be introduced into a well having a formation temperature of 300° F. The scale removal agent is a component of a gelled fluid containing an amine oxide viscoelastic surfactant.