Viscoelastic Solid Surfactant Composition Transparency

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Solution Overview

Problem

Existing solid surfactant compositions lack viscoelastic behavior independent of surfactant phase behavior, leading to stability and dissolution issues in aqueous media, and they are typically opaque, which is not visually appealing to consumers.

Innovation Solution

A viscoelastic, solid surfactant composition is formulated with 0.1 to 70% surfactant and a specific organic compound, such as a diketopiperazine, which provides stability and transparency, allowing for easy dissolution in water and improved aesthetic appeal.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If solid surfactant compositions are formulated conventionally, then they provide stable storage and good cleaning performance, but they are opaque and lack visual appeal to consumers

Engineering Contradiction:
Improvestorage stabilityVSAvoidtransparency
Core Design Contradiction:
Stability of the object's compositionVSIllumination intensity

Solution Approach 1:

The patent changes the physical and chemical parameters of the surfactant composition by incorporating specific organic compounds (diketopiperazines) and controlling molecular weight distributions, which transforms the composition from opaque to transparent while maintaining solid form and storage stability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite material system combining surfactants with specific organic compounds (formula I and II) that have complementary properties, where the organic compounds act as structure-making agents that enable transparency while the surfactant provides cleaning functionality and stability

Inventive Principle:
Principle #40Composite materials

2Ease of operation

If solid surfactant compositions are used in single-dose portions, then convenient dosing is achieved, but rapid dissolution in water is required to avoid substrate damage from overconcentration

Engineering Contradiction:
Improvedosing convenienceVSAvoiddissolution speed
Core Design Contradiction:
Ease of operationVSSpeed

Solution Approach 1:

The patent creates a dynamic system where the surfactant composition maintains structural integrity in solid form for stable dosing, but rapidly transitions to dissolved state upon contact with water through controlled phase behavior and molecular interactions with the added organic compounds

Inventive Principle:
Principle #15Dynamics

3Stability of the object's composition

If viscoelastic behavior is achieved in solid surfactant compositions, then storage stability is improved, but formulation freedom is limited by phase behavior requirements

Engineering Contradiction:
Improvestorage stabilityVSAvoidformulation freedom
Core Design Contradiction:
Stability of the object's compositionVSAdaptability or versatility

Solution Approach 1:

The patent introduces organic compounds with universal structure-making capabilities that can work with various types of surfactants (ionic and nonionic), providing viscoelastic behavior and stability enhancement across different surfactant systems without being limited to specific phase behavior requirements

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition exhibits excellent storage stability, rapid dissolution in water, and a transparent or translucent appearance, enhancing both performance and consumer acceptance.

Implementation Method 1

The viscoelastic solid surfactant composition exhibits virtually no syneresis even upon prolonged storage... the storage modulus is greater than the loss modulus... the composition has a storage modulus between 10³ and 10⁶ Pa

Methodology Applied
Scientific EffectViscoelasticity: Viscoelasticity

Implementation Method 2

it has become an object of the invention to provide solid surfactant compositions, in particular as a single-dose portion in the form of a particulate shaped body, which dissolve well in water or can be dispersed therein upon contact with water

Methodology Applied
Scientific EffectSolvation: Solvation

Data Source

PatentEP3749738B1Viscoelastic, solid surfactant composition
Publication Date: 2024.08.14 HENKEL KGAA
  • EP3749738B1 patent drawing
  • EP3749738B1 patent drawing
  • EP3749738B1 patent drawing

AI summary

The invention relates to a viscoelastic, solid surfactant composition for treating textiles, the composition comprising, based on the total weight thereof, (i) a total amount of 0.1 to 70 wt% of at least one surfactant and (ii) at least one organic compound having a molecular weight of < 1000 g/mol, a solubility in water of less than 0.1 g/L (20 °C, pH 7) and a structure containing a) at least two groups selected from -OH, -NH- or mixtures thereof, and b) at least one carbocyclic structural unit having at least two endocyclic double bonds, in particular at least one carbocyclic, aromatic structural unit, and c) at least one additional cyclic structural unit that comprises at least two carbonyl groups, and (iii) water. The viscoelastic, solid surfactant composition is a readily soluble, aesthetically pleasing and storage-stable form of a solid composition for preparing surfactant-containing liquors.