Viscosified Chelating Fluid for Scale Removal

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Solution Overview

Problem

Scale deposits in downhole wellbore tubulars and subsurface completion equipment, caused by changes in temperature, pressure, and water chemistry, lead to reduced hydrocarbon production by clogging fluid paths and increasing surface roughness, which existing methods fail to address effectively, especially in high-temperature formations where acidic fluids are problematic.

Innovation Solution

A method involving the use of a treatment fluid comprising water, a chelating agent capable of forming a heterocyclic ring with metal and nonmetal ions, and a viscosity-increasing agent to dissolve and remove carbonate scale without acidic or corrosive compositions, enhancing fluid delivery and flowback by increasing viscosity for better coverage and particle carrying capacity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If acidic fluids are used to remove scale deposits, then scale removal effectiveness is improved, but corrosion risk and equipment damage increase

Engineering Contradiction:
Improvescale removal effectivenessVSAvoidcorrosion risk
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical parameters of the treatment fluid by using chelating agents instead of acidic fluids. The chelating agents work through complexation reactions with metal ions in scale deposits, providing effective scale removal without the corrosive effects of low pH fluids. This parameter change resolves the contradiction by maintaining scale removal capability while eliminating corrosion risk.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The chelating agent acts as an intermediary substance that facilitates scale removal through a different mechanism. Instead of using acid to dissolve scale, the chelating agent forms soluble complexes with metal ions in the scale, gradually breaking it down. This intermediary approach achieves the desired scale removal effect without introducing the harmful corrosive properties of acidic fluids.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Object-affected harmful factors

If water-based treatment fluids are used, then corrosion is reduced, but scale removal effectiveness decreases

Engineering Contradiction:
ImprovecorrosionVSAvoidscale removal effectiveness
Core Design Contradiction:
Object-affected harmful factorsVSProductivity

Solution Approach 1:

The patent creates a composite treatment fluid system combining water with chelating agents and viscosity-increasing agents. This composite formulation maintains the low-corrosion advantage of water-based fluids while adding functional components that provide effective scale removal. The chelating agents contribute scale-dissolving capability, while viscosity-increasing agents enhance fluid retention and contact time with scale deposits.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the chemical composition parameters of water-based fluids by incorporating chelating agents. These additives change the fluid's chemical reactivity toward scale deposits, enabling water-based fluids to effectively remove scale through chelation mechanisms rather than relying on acidic properties. This parameter modification resolves the contradiction between low corrosion and effective scale removal.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If treatment fluid viscosity is increased, then fluid retention and coverage are improved, but flow rate through wellbore decreases

Engineering Contradiction:
Improvefluid retentionVSAvoidflow rate
Core Design Contradiction:
ReliabilityVSSpeed

Solution Approach 1:

The patent employs viscosity-increasing agents that can dynamically adjust the fluid's rheological properties. These agents allow the treatment fluid to exhibit higher viscosity during the treatment phase for improved retention and coverage, while enabling adequate flow rates during injection and recovery phases. The dynamic viscosity adjustment resolves the contradiction between retention and flow rate.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The patent modifies the physical parameters of the treatment fluid by adding viscosity-increasing agents. This changes the fluid's viscosity parameter to optimize both retention time on scale deposits and flow characteristics through the wellbore. The controlled viscosity enhancement allows the fluid to adhere better to surfaces while maintaining sufficient mobility for effective delivery and recovery.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method effectively removes calcium and magnesium carbonate scale, reopens tubulars, and enhances hydrocarbon production by dissolving scale under various conditions without using acidic fluids, reducing corrosion risks and maintaining flow efficiency.

Implementation Method 1

a chelating agent capable of forming a heterocyclic ring that contains a metal ion attached to at least two nonmetal ions

Methodology Applied
Scientific EffectChelation:

Data Source

PatentUS8071511B2Methods for stimulating oil or gas production using a viscosified aqueous fluid with a chelating agent to remove scale from wellbore tubulars or subsurface equipment
Publication Date: 2011.12.06 HALLIBURTON ENERGY SERVICES INC

AI summary

A method for treating a wellbore tubular or subsurface completion equipment to help remove scale is provided. In general, the method comprises the steps of: (A) determining the likelihood of the presence of carbonate scale in the wellbore tubular or subsurface completion equipment; (B) forming or providing a treatment fluid comprising: (i) water; (ii) a chelating agent capable of forming a heterocyclic ring that contains a metal ion attached to at least two nonmetal ions; and (iii) a viscosity-increasing agent; and (C) introducing the treatment fluid into the wellbore tubular or the subsurface completion equipment.