Viscosifier Stabilizer Package for High-Temperature Well Fluids

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Solution Overview

Problem

Existing wellbore treatment fluids become unstable at high temperatures due to thermal degradation of polymeric viscosifiers, leading to settling of undissolved solids and density imbalances, which previous attempts to address do not effectively stabilize at temperatures greater than 350°F (177°C).

Innovation Solution

A treatment fluid comprising a thermally stable polymer viscosifier and a stabilizer package, including an oxygen scavenger and a pH adjustor, which increases the thermal stability of the viscosifier to temperatures greater than 350°F (177°C), maintaining fluid stability and consistency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If a polymeric viscosifier is used in wellbore treatment fluid, then the fluid can suspend undissolved solids, but the viscosifier becomes thermally degraded at high temperatures (greater than 350°F), leading to fluid instability

Engineering Contradiction:
Improvefluid stabilityVSAvoidthermal degradation temperature
Core Design Contradiction:
Stability of the object's compositionVSTemperature

Solution Approach 1:

A stabilizer package is introduced as an intermediary substance that protects the polymeric viscosifier from thermal degradation. The stabilizer package includes specific chemicals that scavenge free radicals and inhibit oxidation reactions, thereby mediating between the heat environment and the viscosifier to prevent breakdown.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention changes the chemical parameters of the treatment fluid by adding a stabilizer package that modifies the thermal stability characteristics. This package adjusts the chemical environment to prevent polymer degradation, effectively raising the temperature threshold at which the viscosifier becomes unstable.

Inventive Principle:
Principle #35Parameter changes

2Adaptability or versatility

If the treatment fluid is exposed to high temperatures, then the drilling or treatment operation can proceed in high-temperature wells, but the polymeric viscosifier degrades causing settling of undissolved solids and density imbalances

Engineering Contradiction:
Improvewell temperature rangeVSAvoidviscosifier performance reliability
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The stabilizer package is added beforehand to cushion against the harmful effects of high temperature. It acts as a protective measure in advance, preventing the viscosifier from degrading when exposed to high temperatures, thus maintaining reliable performance in high-temperature well environments.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

3Temperature

If the viscosifier thermal stability is increased using conventional methods, then some temperature improvement is achieved, but the fluid remains unstable at temperatures greater than 350°F

Engineering Contradiction:
Improvethermal stability temperatureVSAvoidfluid composition stability
Core Design Contradiction:
TemperatureVSStability of the object's composition

Solution Approach 1:

The invention creates a composite system by combining the polymeric viscosifier with a multi-component stabilizer package. This composite approach integrates multiple protective mechanisms (free radical scavengers, oxidation inhibitors, pH buffers) to achieve thermal stability at temperatures greater than 350°F, overcoming the limitations of single-method approaches.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The stabilizer package enhances the thermal stability of the viscosifier, allowing the treatment fluid to remain stable and consistent at higher wellbore temperatures, preventing settling and density imbalances, and maintaining viscosity for extended periods.

Implementation Method 1

the first stabilizer is an oxygen scavenger

Methodology Applied
Scientific EffectOxygen scavenging: Absorption (physical)

Implementation Method 2

the second stabilizer is a pH adjustor

Methodology Applied
Scientific EffectpH adjustment:

Implementation Method 3

Viscosifiers are used to suspend undissolved solids in an oil or gas well treatment fluid

Methodology Applied
Scientific EffectViscosification:

Data Source

PatentUS9410070B2Method of treating a high-temperature well with a fluid containing a viscosifier and a stabilizer package
Publication Date: 2016.08.09 HALLIBURTON ENERGY SERVICES INC
  • US9410070B2 patent drawing

AI summary

A treatment fluid for treating a portion of a high-temperature subterranean formation comprises: a base fluid, wherein the base fluid comprises water; a viscosifier, wherein the viscosifier is a polymer, and wherein the viscosifier is thermally stable up to a temperature of 325° F.; and a stabilizer package, wherein the stabilizer package: (A) comprises a first stabilizer and a second stabilizer, wherein the first stabilizer is an oxygen scavenger and the second stabilizer is a pH adjustor; and (B) is capable of increasing the thermal stability of the viscosifier to a temperature greater than 350° F., wherein the portion of the subterranean formation has a bottomhole temperature greater than 350° F. A method of treating a high-temperature subterranean formation comprises introducing the treatment fluid into the portion of the subterranean formation.