Viscosity Gradient in Dishwashing Combination Products

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Solution Overview

Problem

Existing combination products for automatic dishwashing fail to maintain enzyme stability during dosing due to pH fluctuations, as the enzyme-containing and non-enzyme-containing compositions mix, resulting in a pH medium that is not optimal for enzyme activity.

Innovation Solution

The use of separate flowable compositions A and B with adjusted viscosities, where composition A contains 10-75% builder, 0.1-10% enzyme preparation, and 24.9-89.9% water, and composition B contains less than 0.1% enzyme preparation, 0.5-90% water, and at least one detergent ingredient, with viscosities above 1500 mPas, particularly composition B between 3500-6500 mPas, to prevent premature enzyme inactivation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If two separate flowable compositions with different pH values are combined in a packaging material, then enzyme stability during storage is improved, but enzyme stability during dosing deteriorates due to pH mixing

Engineering Contradiction:
Improveenzyme stability during storageVSAvoidenzyme stability during dosing
Core Design Contradiction:
Stability of the object's compositionVSReliability

Solution Approach 1:

The patent adjusts the viscosity parameter of composition B to be higher (3500-6500 mPas) than composition A (1500-3500 mPas), creating a viscosity gradient that controls the mixing behavior during dosing. This parameter change ensures that while the compositions remain separate during storage, they mix in a controlled manner during dosing that preserves enzyme activity.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If composition B has high viscosity to control mixing, then enzyme stability is improved, but dosing speed may be affected

Engineering Contradiction:
Improveenzyme stabilityVSAvoiddosing speed
Core Design Contradiction:
ReliabilityVSSpeed

Solution Approach 1:

The patent applies different viscosity characteristics to different compositions locally: composition A has lower viscosity (1500-3500 mPas) for faster dissolution and enzyme release, while composition B has higher viscosity (3500-6500 mPas) to control mixing and protect enzymes. This local differentiation of rheological properties optimizes both enzyme stability and dosing performance.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This solution ensures that enzymes in composition A are distributed quickly and remain active, while composition B is distributed more slowly, maintaining optimal pH conditions and enhancing cleaning performance, especially for stubborn dirt, without destabilizing the enzymes.

Implementation Method 1

the two compositions A and B each having a viscosity of greater than 1500 mPas, with at least the composition B having a viscosity between 3500 and 6500 mPas

Methodology Applied
Scientific EffectViscosity: Viscometer

Data Source

PatentEP2879973B1Combination product having a high viscosity
Publication Date: 2018.11.21 HENKEL KGAA
  • EP2879973B1 patent drawing
  • EP2879973B1 patent drawing

AI summary

The invention relates to fluid washing or cleaning products which are present as combination products comprising a packaging means and at least two fluid washing or cleaning compositions A and B that are located in said packaging means and that are separate from each other, wherein the two compositions A and B comprise A: 10 to 75 wt% of builder material(s); 0.1 to 10 wt% of enzyme preparation; 24.9 to 89.9 wt% of water; and B: less than 0.1 wt% of enzyme preparation; 0.5 to 90 wt% of water and at least one further ingredient of washing or cleaning products, and which fluid washing or cleaning products have an improved stability if the viscosity of the compositions A and B is above 1500 mPas.