Void-Free Trench Fill Using Angled Seed Layer Etching

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Solution Overview

Problem

Traditional chemical vapor deposition (CVD) methods for filling trenches in semiconductor devices often result in voids and seams due to overhang pinch-off and 'bread-load' effects, making the process time-consuming and complex, and requiring additional surface treatments or pre-existing metal at the trench bottom.

Innovation Solution

The method involves directional etching to remove a seed layer from the sidewalls of trenches at a non-zero angle, allowing for void-free material deposition by maintaining the seed layer on the trench surface, followed by filling with metal using chemical vapor deposition or atomic layer deposition.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If traditional CVD methods are used to fill trenches, then material deposition is achieved, but voids and seams form due to overhang pinch-off and bread-load effects

Engineering Contradiction:
Improvetrench fill uniformityVSAvoidvoid-free deposition
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent applies preliminary action by performing angled ion etching to remove the seed layer from sidewalls before the main CVD deposition process. This pre-treatment modifies the trench geometry to prevent overhang pinch-off during filling, ensuring void-free deposition without requiring complex in-situ adjustments during the actual filling process.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent changes the deposition parameters by using angled ion etching at specific angles (e.g., 15-45 degrees) to selectively remove seed layer from sidewalls while preserving the bottom seed layer. This parameter modification creates optimal conditions for subsequent CVD filling, preventing bread-load effects and ensuring uniform material deposition throughout the trench.

Inventive Principle:
Principle #35Parameter changes

2Ease of manufacture

If traditional CVD trench filling is performed, then material is deposited, but additional surface treatments and pre-existing metal are required

Engineering Contradiction:
Improveprocess simplicityVSAvoidprocess flow complexity
Core Design Contradiction:
Ease of manufactureVSDevice complexity

Solution Approach 1:

The patent extracts the problematic seed layer from the sidewalls using angled ion etching, removing the source of overhang formation and bread-load effects. This extraction simplifies the subsequent deposition process by eliminating the need for complex surface treatments and pre-existing metal structures, reducing overall process flow complexity while maintaining ease of manufacture.

Inventive Principle:
Principle #2Taking out (Extraction)

3Reliability

If angled ion etching is used to remove seed layer from sidewalls, then void-free deposition is achieved, but additional processing steps are added

Engineering Contradiction:
Improvevoid-free trench fillVSAvoidmanufacturing efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent merges the seed layer removal function into the angled ion etching step, which simultaneously prepares the sidewalls for void-free deposition. By combining multiple functions (seed layer removal, surface preparation, and geometry optimization) into a single integrated process step, the patent achieves reliable void-free trench fills without proportionally increasing the number of discrete processing steps, thereby maintaining manufacturing efficiency.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables void-free trench fills with improved conductivity, reduced processing complexity, and increased manufacturing efficiency by eliminating the need for additional lithography and etching procedures, while maintaining uniformity and reducing damage from chemical-mechanical polishing.

Implementation Method 1

removing the seed layer from the first sidewall and the second sidewall using an angled ion etch oriented at a non-zero angle of inclination relative to a perpendicular extending from the trench surface

Methodology Applied
Scientific EffectIon etching: Ion Beam

Implementation Method 2

forming a fill material over the device layer by chemical vapor deposition

Methodology Applied
Scientific EffectChemical vapor deposition: Chemical Vapour Deposition

Implementation Method 3

forming a fill material over the device layer by atomic layer deposition

Methodology Applied
Scientific EffectAtomic layer deposition: Physical Vapour Deposition

Data Source

PatentUS12131948B2Techniques for void-free material depositions
Publication Date: 2024.10.29 APPLIED MATERIALS INC
  • US12131948B2 patent drawing
  • US12131948B2 patent drawing
  • US12131948B2 patent drawing

AI summary

Embodiments herein include void-free material depositions on a substrate (e.g., in a void-free trench-filled (VFTF) component) obtained using directional etching to remove predetermined portions of a seed layer covering the substrate. In several embodiments, directional etching followed by selective deposition can enable fill material (e.g., metal) patterning in tight spaces without any voids or seams. Void-free material depositions may be used in a variety of semiconductor devices, such as transistors, dual work function stacks, dynamic random-access memory (DRAM), non-volatile memory, and the like.