Voltage Switchable Dielectric Material Using Conductor-on-Conductor Core Shelled Particles

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Solution Overview

Problem

Voltage switchable dielectric (VSD) composites loaded to just below the percolation threshold face issues with high current leakage and low loading levels, while materials loaded above the threshold are not conductive enough to provide adequate electrostatic discharge (ESD) protection, necessitating a balance between 'on' and 'off' state resistance.

Innovation Solution

The use of core shelled particles with conductive cores and multilayered or heterogeneous shells, which can be tuned to optimize electrical characteristics, allowing for higher loading concentrations without losing insulative properties at low voltages and conducting at higher voltages, thereby enhancing ESD protection.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If VSD composites are loaded to just below the percolation threshold with conductive particles, then insulative properties at low voltages are maintained, but current leakage increases and loading levels remain low

Engineering Contradiction:
Improveinsulative propertiesVSAvoidcurrent leakage
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent applies local quality by creating particles with non-uniform conductivity distribution through core-shell structures. The conductive core provides high conductivity while the insulating shell provides low conductivity, and their ratio can be adjusted to optimize the balance between insulative properties and current leakage resistance.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent uses composite materials by combining conductive particles with insulating particles to form VSD composites. This composite structure allows the material to exhibit voltage-dependent properties, being insulative at low voltages and conductive at high voltages, while controlling both leakage current and loading levels.

Inventive Principle:
Principle #40Composite materials

2Reliability

If higher particle loading concentrations are used in VSD composites, then ESD protection is improved, but leakage current increases

Engineering Contradiction:
ImproveESD protectionVSAvoidleakage current
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent applies local quality by creating particles with non-uniform conductivity distribution through core-shell structures. The conductive core provides high conductivity while the insulating shell provides low conductivity, and their ratio can be adjusted to optimize the balance between insulative properties and current leakage resistance.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent uses composite materials by combining conductive particles with insulating particles to form VSD composites. This composite structure allows the material to exhibit voltage-dependent properties, being insulative at low voltages and conductive at high voltages, while controlling both leakage current and loading levels.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach reduces leakage current and enables higher particle loading concentrations, achieving lower clamp voltages and improved ESD protection by maintaining high resistance at low biases and switching to a conductive state at elevated voltages.

Implementation Method 1

Voltage switchable dielectric (VSD) materials are materials that are insulative at low voltages and conductive at higher voltages

Methodology Applied
Scientific EffectDielectric breakdown: Dielectric

Implementation Method 2

a layer of polymer is filled with high levels of metal particles to very near the percolation threshold

Methodology Applied
Scientific EffectPercolation threshold: Conduction (electrical)

Implementation Method 3

These materials are used for transient protection of electronic devices, most notably electrostatic discharge protection (ESD) and electrical overstress (EOS)

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Data Source

PatentUS9208931B2Voltage switchable dielectric material containing conductor-on-conductor core shelled particles
Publication Date: 2015.12.08 LITTELFUSE INC
  • US9208931B2 patent drawing
  • US9208931B2 patent drawing
  • US9208931B2 patent drawing

AI summary

A composition of voltage switchable dielectric (VSD) material that comprises a concentration of core shelled particles that individually comprise a conductor core and a conductor shell, so as to form a conductor-on-conductor core shell particle constituent for the VSD material.