Voltammetric Drug Sensor With Membrane Extraction for Infusion Feedback

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Solution Overview

Problem

Existing pharmacokinetic models for computer-controlled infusion pumps do not account for individual patient drug-response, leading to inaccuracies in drug concentration and effect-time profiles, necessitating a sensor device for real-time bioavailable drug concentration detection.

Innovation Solution

An electrochemical voltammetric sensor device with a water-immiscible coating on electrodes, capable of partitioning hydrophobic drugs like propofol from complex solutions, is integrated into a drug delivery system for real-time feedback control.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Extent of automation

If pharmacokinetic models are used for drug delivery control, then drug delivery can be automated, but measurement precision of bioavailable drug concentration is insufficient

Engineering Contradiction:
Improvedrug delivery automationVSAvoidbioavailable drug concentration detection
Core Design Contradiction:
Extent of automationVSMeasurement precision

Solution Approach 1:

The patent introduces a membrane as an intermediary component between the electrode and the aqueous sample. This membrane selectively partitions hydrophobic drugs from the aqueous environment into its hydrophobic phase, enabling the electrochemical electrode to detect drug concentrations that would otherwise be undetectable or poorly detectable in aqueous solutions. This intermediary mechanism resolves the contradiction by enabling precise measurement of bioavailable hydrophobic drug concentrations, which is the critical missing element for accurate automated drug delivery control.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Loss of time

If electrochemical sensors detect hydrophobic drugs in aqueous solutions, then real-time detection is achieved, but detection accuracy is reduced due to interference from chloride ions and other molecules

Engineering Contradiction:
Improvedetection timeVSAvoiddrug concentration detection accuracy
Core Design Contradiction:
Loss of timeVSMeasurement precision

Solution Approach 1:

The patent extracts the hydrophobic drug from the complex aqueous environment by utilizing the membrane's selective partitioning capability. The membrane separates the hydrophobic drug molecules from the aqueous phase containing interfering ions and molecules, concentrating them in the membrane phase where they can be detected by the electrode without interference. This extraction mechanism enables accurate real-time detection by removing the source of measurement errors while maintaining rapid response time.

Inventive Principle:
Principle #2Taking out (Extraction)

3Reliability

If a sensor device is integrated into the drug delivery system, then feedback control is enabled, but device complexity increases

Engineering Contradiction:
Improvefeedback control capabilityVSAvoidsensor integration complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent merges the sensing function directly into the drug delivery system by integrating the membrane-coated electrochemical sensor with the infusion pump. This combination creates a unified system where drug delivery and real-time concentration monitoring occur through a single integrated device, enabling closed-loop feedback control. The merging approach reduces overall system complexity compared to separate sensing and delivery systems, while providing reliable real-time feedback for precise drug delivery control.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Accurately detects sub-micromolar drug concentrations in seconds, overcoming interference from chloride ions and other molecules, enabling precise drug delivery adjustments based on bioavailable drug levels.

Implementation Method 1

the coating partitions a hydrophobic drug from a fluid sample

Methodology Applied
Scientific EffectPartitioning: Liquid-Liquid Extraction

Implementation Method 2

detecting an oxidation/reduction current within the coating

Methodology Applied
Scientific EffectOxidation-reduction reaction: Redox Reactions

Data Source

PatentEP3629928B1Method and device for detection of bioavailable drug concentration in a fluid sample
Publication Date: 2025.11.05 UNIVERSITY OF TENNESSEE RESEARCH FOUNDATION
  • EP3629928B1 patent drawingFigure 1~4
  • EP3629928B1 patent drawingFigure 5~8
  • EP3629928B1 patent drawingFigure 9~12

AI summary

The invention relates to a method for the controlled delivery of a drug as a function of bioavailable drug concentration, a sensor device for detecting bioavailable drug concentration, and a delivery device that controls delivery of the drug based on the real-time detection of bioavailable drug concentration.