Portable VRFB Electrolyte Purification for On-Site Commissioning

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current methods for purifying vanadium redox flow battery (VRFB) electrolytes are inadequate for ensuring on-site, efficient removal of impurities that can foul battery components, particularly when dealing with gel electrolytes shipped in a densified form that require dilution on-site.

Innovation Solution

A portable commissioning system integrated with a conventional VRFB system, featuring a pump and a fine-media filter (rated less than 2 microns) for on-site purification, which includes a thermal management system to enhance precipitation and a rinsing loop for filter maintenance, ensuring effective impurity separation and electrolyte purification.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a dedicated electrolyte-purification system is used to purify VRFB electrolyte, then impurity removal effectiveness is improved, but system complexity and cost increase

Engineering Contradiction:
Improveimpurity removal effectivenessVSAvoidsystem complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent combines the electrolyte purification function with the existing VRFB system by integrating a portable commissioning system that uses the battery's own components (pumps, tanks, cell stack) for purification. This merging approach eliminates the need for a completely separate dedicated purification system, reducing overall system complexity while maintaining purification effectiveness.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The portable commissioning system is designed to perform multiple functions: it can purify electrolyte, charge the battery, and condition the electrolyte using the VRFB's existing infrastructure. This multi-functionality reduces the need for separate dedicated equipment, addressing the complexity issue while maintaining reliable impurity removal.

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Ease of manufacture

If electrolyte is purified off-site using conventional methods, then purification process is simpler, but on-site impurity removal capability is insufficient

Engineering Contradiction:
Improvepurification process simplicityVSAvoidon-site purification capability
Core Design Contradiction:
Ease of manufactureVSAdaptability or versatility

Solution Approach 1:

The system performs preliminary purification actions during the commissioning phase before the battery enters normal operation. The portable commissioning system prepares the electrolyte by removing impurities in advance, ensuring the battery starts with clean electrolyte. This preliminary action approach combines simple off-site preparation with on-site purification capability.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The VRFB system is equipped with its own purification capability through the integrated portable commissioning system, allowing it to purify its own electrolyte on-site without requiring external dedicated purification equipment. This self-service approach enhances adaptability while maintaining process simplicity through the use of existing system components.

Inventive Principle:
Principle #25Self-service

3Productivity

If gel electrolyte is shipped in densified form, then shipping efficiency is improved, but on-site preparation complexity increases

Engineering Contradiction:
Improveshipping efficiencyVSAvoidon-site preparation complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The electrolyte is prepared in a densified gel form during manufacturing, which is then shipped efficiently. The actual dilution and final preparation actions are performed preliminarily during the commissioning phase using the portable system, combining the shipping efficiency of dense form with manageable on-site preparation.

Inventive Principle:
Principle #10Preliminary action

4Reliability

If fine-media filter with rating less than 2 microns is used, then impurity separation effectiveness is improved, but filter clogging and maintenance frequency increase

Engineering Contradiction:
Improveimpurity separation effectivenessVSAvoidfilter maintenance frequency
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The system performs preliminaryç²— filtration using larger pore size filters before the fine-media filter during the purification process. This preliminary action removes bulk impurities first, reducing the load on the fine-media filter and extending its service life while maintaining high separation effectiveness when needed.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The system includes monitoring capabilities to detect when the fine-media filter requires maintenance by measuring pressure differential across the filter. This feedback mechanism allows for timely maintenance scheduling based on actual filter condition rather than fixed intervals, optimizing maintenance frequency while ensuring continuous effective operation.

Inventive Principle:
Principle #23Feedback

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system achieves efficient on-site purification of VRFB electrolytes, reducing impurity-related fouling and extending the lifespan of battery components, while allowing for localized production and cost savings through on-site electrolyte mixing and purification.

Implementation Method 1

a thermal management system to enhance precipitation

Methodology Applied
Scientific EffectPrecipitation: Precipitation

Implementation Method 2

a fine-media filter (rated less than 2 microns) for on-site purification

Methodology Applied
Scientific EffectFiltration: Filter (physical)

Data Source

PatentEP4492512A1System and method for on-site VRFB electrolyte purification
Publication Date: 2025.01.15 STORION ENERGY LLC
  • EP4492512A1 patent drawingFigure 1
  • EP4492512A1 patent drawingFigure 2
  • EP4492512A1 patent drawingFigure 3~4A

AI summary

There is provided a VRFB commissioning subsystem and process to purify a VRFB electrolyte on-site. In an embodiment, a conventional VRFB system is combined with a novel portable commissioning system for preparing and provisioning a purified electrolyte solution to the VRFB. This on-site purification is especially synergistic with shipping of electrolyte as a gel since the electrolyte can be produced in a densified form and not diluted with water until it is on site.