Vanadium Selenide Carbon Cellulose Composite for Battery Electrodes

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Solution Overview

Problem

Vanadium diselenide, used as a negative electrode material in potassium ion batteries, suffers from poor conductivity and restacking, leading to rapid capacity decline due to volume expansion and agglomeration, which limits its cycling stability and rate performance.

Innovation Solution

A vanadium selenide/carbon cellulose composite is synthesized using a hydrothermal, freeze-drying, and high-temperature pyrolysis method, with a mass ratio of 50-60% VSe2 and 40-50% carbon cellulose, enhancing electron conductivity and inhibiting volume expansion and agglomeration.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If vanadium diselenide is used as negative electrode material, then moderate potassium-embedded voltage and good safety are achieved, but poor conductivity and restacking lead to rapid capacity decline

Engineering Contradiction:
Improvecycling stabilityVSAvoidcapacity retention
Core Design Contradiction:
ReliabilityVSLoss of energy

Solution Approach 1:

The patent creates a composite material consisting of vanadium diselenide (VSe2) nanosheets combined with conductive carbon materials (such as reduced graphene oxide or carbon nanotubes). This composite structure leverages the electrochemical activity of VSe2 while the carbon component provides conductivity pathways and prevents restacking, thereby resolving the contradiction between achieving moderate potassium-embedded voltage with good safety and maintaining capacity retention through improved conductivity and structural stability.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent employs thin film structures where VSe2 nanosheets are dispersed and stabilized within a carbon matrix. The carbon component acts as a flexible conductive network that maintains electrical contact between VSe2 particles during cycling, preventing restacking and capacity fade while preserving the electrochemical benefits of VSe2.

Inventive Principle:
Principle #30Flexible shells and thin films

2Quantity of substance

If vanadium diselenide is used as negative electrode material, then high specific capability is achieved, but volume expansion and agglomeration occur during charging and discharging

Engineering Contradiction:
Improvespecific capabilityVSAvoidstructural integrity
Core Design Contradiction:
Quantity of substanceVSStability of the object's composition

Solution Approach 1:

The patent constructs a composite where VSe2 nanosheets are embedded in a robust carbon framework. The carbon component provides structural integrity and prevents agglomeration of VSe2 particles during the volume expansion and contraction that occurs during potassium ion insertion and extraction. This maintains both the high specific capability of VSe2 and the structural stability needed to prevent degradation.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent creates a heterogeneous structure where VSe2 nanosheets provide localized high-capacity regions while the carbon matrix provides distributed structural support and conductivity throughout the electrode. This local quality differentiation allows the VSe2 to deliver high specific capability while the carbon network maintains overall structural integrity during cycling.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composite significantly improves the rate performance and cycling stability of the material, maintaining capacity and structural integrity over multiple cycles.

Implementation Method 1

a hydrothermal method, a freeze drying method and a high-temperature pyrolysis method

Methodology Applied
Scientific EffectHydrothermal synthesis:

Implementation Method 2

a hydrothermal method, a freeze drying method and a high-temperature pyrolysis method

Methodology Applied
Scientific EffectFreeze drying: Freeze Drying

Implementation Method 3

a hydrothermal method, a freeze drying method and a high-temperature pyrolysis method

Methodology Applied
Scientific EffectPyrolysis: Pyrolysis

Data Source

PatentUS20220278312A1Vanadium selenide/carbon cellulose composite as well as preparation method and application thereof
Publication Date: 2022.09.01 GUANGDONG UNIV OF TECH
  • US20220278312A1 patent drawing
  • US20220278312A1 patent drawing
  • US20220278312A1 patent drawing

AI summary

The disclosure provides a preparation method of a vanadium selenide/carbon cellulose composite, belonging to the technical fields of electrode materials of potassium ion batteries and preparation technologies thereof. Through compounding of carbon, carbon cellulose and vanadium diselenide (VSe2), a synergistic effect occurs between two components, and carbon cellulose-carbon coating is capable of increasing electron conductivity and potassium ion diffusion rate of a material while inhibiting the agglomeration of vanadium diselenide (VSe2). Therefore, the prepared vanadium selenide/carbon cellulose composite has excellent electrochemical performance and exhibits outstanding rate performance and cycling stability. The method is simple in process, low in cost, environmentally friendly, and suitable for large-scale industrial production.