Wafer Bonding via Plasma Activation and Hydrophilization

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Solution Overview

Problem

Existing joint systems for semiconductor wafers face issues such as wafer breakage and positional displacement due to high pressure, and low joining strength, leading to reduced throughput in wafer joint processing.

Innovation Solution

A joint system that includes a surface activation apparatus to activate the wafer surfaces, a surface hydrophilizing apparatus to form hydroxyls, and a joint apparatus that uses Van der Waals force and hydrogen bonding for strong bonding without the need for physical pressing, along with a transfer-in/out station for efficient processing and handling of multiple wafers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If work rollers press two wafers together to join them, then the wafers are joined together, but the wafers may break due to the load

Engineering Contradiction:
Improvejoining strengthVSAvoidwafer integrity
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent replaces the mechanical pressing system with a chemical bonding system. Instead of using work rollers to physically press wafers together, the invention uses plasma treatment to activate wafer surfaces and create chemical bonds (Van der Waals forces and hydrogen bonding) between opposing surfaces. This eliminates mechanical contact and associated damage risks while achieving strong bonding.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the bonding mechanism from mechanical to chemical by modifying surface properties through plasma treatment. The plasma process alters surface energy and chemistry parameters, creating activated surfaces that form strong chemical bonds without requiring mechanical pressure. This parameter change enables bonding without the harmful mechanical loads that cause wafer breakage.

Inventive Principle:
Principle #35Parameter changes

2Strength

If wafers are pressed while deviated from vertical direction, then the wafers are joined together, but positional displacement of the wafers occurs

Engineering Contradiction:
Improvejoining strengthVSAvoidpositional accuracy
Core Design Contradiction:
StrengthVSManufacturing precision

Solution Approach 1:

The patent eliminates the need for mechanical pressing alignment by replacing the mechanical bonding process with a chemical bonding process. Since plasma-activated surfaces bond through molecular forces rather than mechanical contact, precise vertical alignment is no longer critical. This substitution removes the source of positional displacement problems associated with mechanical pressing.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Strength

If it takes a lot of time to press the two wafers together to join them, then the wafers are joined together, but the throughput of the wafer joint processing is reduced

Engineering Contradiction:
Improvejoining strengthVSAvoidprocessing throughput
Core Design Contradiction:
StrengthVSProductivity

Solution Approach 1:

The patent replaces the time-consuming mechanical pressing operation with a rapid plasma treatment and bonding process. Plasma activation occurs quickly, and the subsequent bonding happens automatically when wafers are brought into contact, eliminating the prolonged pressing time required in mechanical systems. This dramatically increases processing throughput while maintaining bond strength.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent skips the lengthy mechanical pressing step entirely by using plasma-activated chemical bonding. The plasma treatment prepares surfaces in seconds, and bonding occurs immediately upon contact without requiring extended pressing time. This rushes through the bonding process efficiently, maximizing throughput.

Inventive Principle:
Principle #21Skipping (Rushing through)

4Productivity

If the temporary joint is performed by generating the Van der Waals force between the activated front surfaces, then the wafers are temporarily joined, but the joining strength is insufficient

Engineering Contradiction:
Improveprocessing speedVSAvoidjoining strength
Core Design Contradiction:
ProductivityVSStrength

Solution Approach 1:

The patent enhances the bonding strength by modifying surface chemistry parameters through plasma treatment. The plasma process creates highly reactive surface groups and increases surface energy, which strengthens both Van der Waals forces and introduces hydrogen bonding capabilities. This parameter change transforms the bonding mechanism from weak physical adsorption to strong chemical bonding.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite bonding mechanism that combines multiple interaction forces: Van der Waals forces from plasma activation and hydrogen bonding from hydroxyl groups on the activated surfaces. This composite approach integrates multiple bonding mechanisms to achieve superior overall bond strength while maintaining rapid processing.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances the throughput of substrate joint processing by eliminating the risk of wafer breakage and positional displacement, while achieving strong and reliable bonding through Van der Waals forces and hydrogen bonding, thereby improving the efficiency and reliability of wafer joining.

Implementation Method 1

the beam irradiation means activates the front surfaces (joint surfaces) of the wafers to generate the Van der Waals force between the front surfaces of the two wafers

Methodology Applied
Scientific EffectVan der Waals force: Van der Waals Force

Implementation Method 2

a surface hydrophilizing apparatus hydrophilizing the front surface of the substrate activated in the surface activation apparatus

Methodology Applied
Scientific EffectHydrophilization: Hydrophile

Implementation Method 3

the hydroxyls on the hydrophilized front surfaces of the substrates are hydrogen-bonded, whereby the substrates can be strongly joined together

Methodology Applied
Scientific EffectHydrogen bonding: Chemical Bonding

Data Source

PatentUS8795463B2Joint system, joint method, program and computer storage medium
Publication Date: 2014.08.05 TOKYO ELECTRON LTD
  • US8795463B2 patent drawing
  • US8795463B2 patent drawing
  • US8795463B2 patent drawing

AI summary

A joint system includes: a transfer-in/out station capable of holding a plurality of substrates or a plurality of superposed substrates, and transferring-in/out the substrates or superposed substrates to/from a processing station; and the processing station performing predetermined processing on the substrates and joining the substrates together. The processing station includes: a surface activation apparatus activating a front surface of the substrate; a surface hydrophilizing apparatus hydrophilizing and cleaning the front surface of the substrate; a joint apparatus joining the substrates together; and a transfer region for transferring the substrate or superposed substrate to the surface activation apparatus, the surface hydrophilizing apparatus, and the joint apparatus.