Wafer Dicing Surfactant Composition for Particle and Residue Control

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Solution Overview

Problem

Silicon particles scattered during wafer dicing adhere to the wafer surface, reducing yield and necessitating a cleanser that prevents residue formation and enhances cleansing ability.

Innovation Solution

A cleansing composition for wafer dicing comprising a surfactant with a hydrophilic moiety, such as monosaccharides or disaccharides, and a hydrophobic moiety, including a C4 to C20 polyethylene glycol group substituted with an alkyl benzyl group, is used to prevent silicon particle adsorption and enhance cleansing.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If a conventional cleanser is used to remove silicon particles, then the wafer surface can be cleaned, but residue is left on the wafer surface

Engineering Contradiction:
Improvesilicon particle adhesionVSAvoidcleanser residue
Core Design Contradiction:
Object-affected harmful factorsVSObject-generated harmful factors

Solution Approach 1:

The patent changes the chemical parameters of the cleanser by specifying a particular surfactant structure with hydrophilic moiety (monosaccharide or disaccharide) and hydrophobic moiety (C4-C20 polyethylene glycol group substituted with alkyl benzyl group). This parameter change in molecular structure enables effective silicon particle removal while preventing residue formation on the wafer surface.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses a composite surfactant molecule combining hydrophilic and hydrophobic moieties. The hydrophobic part interacts with silicon particles for removal, while the hydrophilic part ensures water solubility and prevents residue, creating a composite material that simultaneously achieves cleaning and residue-free surfaces.

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If a cleanser with strong cleansing ability is used, then organic contaminants are removed effectively, but residue formation increases

Engineering Contradiction:
Improveorganic contaminant removalVSAvoidresidue on wafer surface
Core Design Contradiction:
Object-affected harmful factorsVSObject-generated harmful factors

Solution Approach 1:

The patent optimizes the molecular weight and structural parameters of the surfactant to achieve balanced cleansing power and low residue. The specific range of polyethylene glycol chain length (C4-C20) and the choice of monosaccharide/disaccharide hydrophilic groups are parameter changes that enable strong organic contaminant removal while maintaining low residue formation.

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If the cleanser composition is simplified, then manufacturing cost decreases, but cleansing ability for both silicon particles and organic contaminants is reduced

Engineering Contradiction:
Improvemanufacturing costVSAvoidcleansing ability
Core Design Contradiction:
Ease of manufactureVSObject-affected harmful factors

Solution Approach 1:

The patent specifies precise parameter ranges for the surfactant structure (polyethylene glycol chain length C4-C20, specific hydrophilic groups) to achieve optimal cleansing performance. These parameter changes ensure that the simplified composition maintains high cleansing ability for both silicon particles and organic contaminants while being cost-effective to manufacture.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition effectively prevents silicon particle adhesion and residue formation on the wafer surface, maintaining high yield and cleansing efficiency.

Implementation Method 1

Silicon particles, which are scattered when the wafer is cut by a blade during the wafer dicing process, are adsorbed on a top surface of the wafer or on a pad, resulting in a decrease in yield for the manufacturing process. A cleanser for wafer dicing may be used to prevent these problems.

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

a surfactant that includes a hydrophilic moiety and a hydrophobic moiety, and a solvent. The hydrophilic moiety is selected from monosaccharides, disaccharides, or derivatives thereof, and the hydrophobic moiety includes a C4 to C20 polyethylene glycol group, which is substituted with an alkyl benzyl group.

Methodology Applied
Scientific EffectSurfactant: Surfactant

Data Source

PatentUS20250223514A1Cleansing composition for wafer dicing
Publication Date: 2025.07.10 SAMSUNG ELECTRONICS CO LTD
  • US20250223514A1 patent drawing
  • US20250223514A1 patent drawing
  • US20250223514A1 patent drawing

AI summary

A cleansing composition for wafer dicing includes a surfactant that contains a hydrophilic moiety and a hydrophobic moiety, and a solvent. The hydrophilic moiety is selected from monosaccharides, disaccharides, or derivatives thereof. The hydrophobic moiety includes a C4 to C20 polyethylene glycol group substituted with an alkyl benzyl group.