Wafer Edge Cleaning With Gas Clusters in Vacuum Processing

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Solution Overview

Problem

The peripheral portion of semiconductor wafers experiences acute silicon irregularities and unwanted particle deposition during etching processes, which are difficult to remove using conventional plasma cleaning due to anisotropic plasma properties, leading to contamination and damage to the device area.

Innovation Solution

A substrate cleaning apparatus that uses nozzle units to eject gas clusters with higher pressure than the processing chamber, forming aggregates of atoms and/or molecules to remove unnecessary substances from the peripheral portion of the substrate without affecting the effective area, utilizing a vacuum processing system with a moving mechanism to precisely target and clean the peripheral region.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If plasma cleaning is used to remove acute silicon irregularities, then cleaning is performed, but the cleaning is ineffective due to anisotropic property of plasma

Engineering Contradiction:
Improveremoval of acute silicon irregularitiesVSAvoidcleaning effectiveness
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The invention changes the physical state and properties of the cleaning medium from plasma to gas clusters. By using gas clusters instead of plasma, the anisotropic limitation is overcome while maintaining cleaning capability. The gas clusters are generated by adiabatic expansion of cleaning gas, creating a different interaction mechanism with the silicon surface that effectively removes acute irregularities.

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If brush cleaning is used to scrape off protrusions, then mechanical removal is achieved, but the protrusions cannot be scraped off

Engineering Contradiction:
Improveremoval of peripheral protrusionsVSAvoidcleaning process feasibility
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The invention replaces the mechanical brush cleaning system with a gas cluster-based cleaning system. The gas clusters, generated through adiabatic expansion, provide the necessary mechanical impact to remove protrusions without requiring physical contact from brushes, thereby achieving effective removal while simplifying the cleaning mechanism.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Manufacturing precision

If CMP is used to remove protrusions, then the protrusions are removed, but the wafer surface may be contaminated

Engineering Contradiction:
Improveremoval of acute silicon irregularitiesVSAvoidwafer surface contamination
Core Design Contradiction:
Manufacturing precisionVSObject-affected harmful factors

Solution Approach 1:

The invention replaces CMP mechanical polishing with gas cluster cleaning. The gas clusters remove protrusions through controlled impact and chemical interaction without the mechanical contact that causes contamination in CMP processes. This substitution eliminates the contamination issue while maintaining the ability to remove acute silicon irregularities.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

4Manufacturing precision

If dry cleaning with plasma is performed, then cleaning is achieved, but cleaning gas needs to be changed depending on materials and device area is damaged

Engineering Contradiction:
Improvecleaning of peripheral portionVSAvoidcleaning process complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The gas cluster cleaning system provides a universal cleaning mechanism that can handle multiple materials and deposit types without requiring changes in cleaning gas. The gas clusters effectively remove various contaminants including organic deposits, inorganic materials, and acute silicon irregularities through a single cleaning process, eliminating the complexity of selecting and switching between different cleaning gases.

Inventive Principle:
Principle #6Universality (Multi-functionality)

5Manufacturing precision

If wet etching is performed to remove deposits, then deposit removal is achieved, but re-adhesion of removed deposit occurs

Engineering Contradiction:
Improveremoval of peripheral depositsVSAvoidprevent re-adhesion of deposits
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The invention replaces wet etching with gas cluster cleaning. The gas clusters remove deposits through physical impact and chemical interaction without leaving residues that could re-adhere. The cleaning process effectively eliminates deposits from the peripheral portion and prevents re-adhesion, avoiding the problems associated with wet etching.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Effectively removes needle-shaped protrusions and deposits from the wafer's peripheral area through physical and chemical action of gas clusters, preventing re-adhesion and minimizing contamination, while maintaining the integrity of the device area.

Implementation Method 1

the nozzle unit discharges a cleaning gas having a pressure higher than that in the processing chamber so that the cleaning gas is adiabatically expanded to form aggregates of atoms and/or molecules

Methodology Applied
Scientific EffectAdiabatic expansion: Adiabatic Cooling

Data Source

PatentUS20120247670A1Substrate cleaning apparatus and vacuum processing system
Publication Date: 2012.10.04 TOKYO ELECTRON LTD
  • US20120247670A1 patent drawing
  • US20120247670A1 patent drawing
  • US20120247670A1 patent drawing

AI summary

A substrate cleaning apparatus includes a supporting unit, provided in a processing chamber having a gas exhaust port, for supporting a substrate; one or more nozzle units, each for ejecting gas clusters to a peripheral portion of the substrate supported by the supporting unit to remove unnecessary substances from the peripheral portion; and a moving mechanism for changing relative positions of the supporting unit and the nozzle unit during ejecting the gas clusters. Each nozzle unit discharges a cleaning gas having a pressure higher than that in the processing chamber so that the cleaning gas is adiabatically expanded to form aggregates of atoms and/or molecules.