Photo-Releasable Wafer Laminate for Clean Substrate Separation

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Solution Overview

Problem

Current semiconductor wafer lamination techniques face challenges in achieving easy separation of support substrates and semiconductor substrates without deformation or residue, especially during polishing, and require a release mechanism that withstands stress during processing.

Innovation Solution

A laminate structure comprising a semiconductor substrate, a light-transmissive support substrate, and an adhesive and release layer with a compound having a styrylene structure that absorbs light to facilitate easy separation and is soluble in cleaning agents, using a release agent composition with a siloxane structure for the release layer.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If a strong adhesive force is used to withstand polishing stress, then the semiconductor wafer remains stable during polishing, but the wafer becomes difficult to remove from the support without deformation

Engineering Contradiction:
Improveadhesive forceVSAvoidease of removal
Core Design Contradiction:
StrengthVSEase of operation

Solution Approach 1:

The adhesive layer's properties are changed by irradiating it with light, causing a photochemical reaction that reduces its adhesive force. This allows the bonding strength to be dynamically adjusted from strong (during polishing) to weak (during removal) by changing the light irradiation parameter

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The adhesive layer is pre-designed to contain photo-sensitive components that will undergo a chemical change when exposed to light. This preliminary preparation enables the adhesive force to be reduced on demand, facilitating easy removal after the bonding has served its purpose during polishing

Inventive Principle:
Principle #10Preliminary action

2Ease of operation

If conventional release methods are used, then the semiconductor wafer can be removed from the support, but residue remains on the wafer surface requiring additional cleaning steps

Engineering Contradiction:
Improveease of removalVSAvoidresidue
Core Design Contradiction:
Ease of operationVSObject-generated harmful factors

Solution Approach 1:

The release layer undergoes a phase transition or chemical decomposition when irradiated with light, transforming from a solid adhesive state to a soluble or volatile state. This phase change allows the release layer to be easily removed without leaving residue on the semiconductor wafer surface

Inventive Principle:
Principle #36Phase transitions

Solution Approach 2:

The release layer is designed as a separate, extractable component that can be selectively removed from the semiconductor wafer surface. By using light-irradiated decomposition, the release layer materials are extracted or decomposed into soluble products that can be cleaned away, leaving no harmful residue

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables easy separation of substrates after light irradiation and effective cleaning of the release layer residue, ensuring minimal deformation and efficient processing of semiconductor substrates.

Implementation Method 1

the release layer absorbs light emitted from the support substrate side

Methodology Applied
Scientific EffectLight absorption: Absorption (EM radiation)

Implementation Method 2

a compound having: a first structure that absorbs the light and contributes to facilitating the semiconductor substrate and the support substrate to be released by absorbing the light

Methodology Applied
Scientific EffectPhotochemical reaction: Photopolymerisation

Data Source

PatentUS20240208179A1Laminate, release agent composition, and method for manufacturing processed semiconductor substrate
Publication Date: 2024.06.27 NISSAN CHEM CORP
  • US20240208179A1 patent drawing
  • US20240208179A1 patent drawing
  • US20240208179A1 patent drawing

AI summary

A laminate includes: a semiconductor substrate; a light-transmissive support substrate; and an adhesive layer and a release layer disposed between the semiconductor substrate and the support substrate. The release layer is formed of a release agent composition containing a compound having: a first structure that absorbs the light and contributes to facilitating the semiconductor substrate and the support substrate to be released by absorbing the light; and a siloxane structure as a second structure.