Wafer Metal Contamination Analysis With ICP-MS Interference Correction

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Solution Overview

Problem

Inductively-coupled plasma-mass spectrometry (ICP-MS) for wafer contamination analysis faces interference issues between metals with similar masses, leading to inaccurate contamination level measurements and reduced reliability.

Innovation Solution

A method and apparatus using a correlation equation to correct contamination levels by accounting for interference between metals like Ni and Fe, employing a controller to obtain and apply correction values based on verified samples.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If ICP-MS is used for contamination analysis, then metal contamination levels can be detected, but interference phenomenon occurs between elements of similar mass causing distorted measurements

Engineering Contradiction:
Improvecontamination level measurement accuracyVSAvoidmeasurement reliability
Core Design Contradiction:
Measurement precisionVSReliability

Solution Approach 1:

The patent introduces a correlation equation as an intermediary computational model that relates the contamination levels of interfering metals (e.g., Fe-56 and Ni-58). By substituting the measured contamination level of one metal into the correlation equation, a correction value is obtained that accounts for the interference effect, thereby mediating between the raw measurement and the true contamination level.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the parameter representation by introducing a correction value derived from correlation equations. Instead of directly using the raw contamination level measurement, the method transforms the measurement by applying a correction factor (y = 0.143x + 0.055) that adjusts the measured value to compensate for interference effects, thus changing the parameter from raw measurement to corrected contamination level.

Inventive Principle:
Principle #35Parameter changes

2Measurement precision

If correction values are calculated using correlation equations, then measurement accuracy is improved, but additional calculation steps and data processing are required

Engineering Contradiction:
Improvecontamination level measurement accuracyVSAvoiddata processing complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent applies preliminary action by pre-establishing correlation equations based on interference relationships between metals before actual contamination analysis. The correlation equations (e.g., y = 0.143x + 0.055 for Fe-56 and Ni-58) are determined in advance through verification using mixed solutions, so that during actual measurement, only simple substitution and calculation are needed rather than complex real-time analysis.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Accurately determines metal contamination levels by correcting for interference, enhancing reliability and precision in wafer analysis.

Implementation Method 1

The various metals on the wafer are separated by mass by the mass separator of ICP-MS

Methodology Applied
Scientific EffectMass separation:

Implementation Method 2

An inductively-coupled plasma-mass spectrometry (hereinafter referred to as ICP-MS) is used for contamination analysis

Methodology Applied
Scientific EffectInductively-coupled plasma: Electromagnetic Induction

Data Source

PatentUS12596078B2Apparatus for analyzing metal contamination of a wafer and a method thereof
Publication Date: 2026.04.07 SK SILTRON CO LTD
  • US12596078B2 patent drawing
  • US12596078B2 patent drawing
  • US12596078B2 patent drawing

AI summary

A method for analyzing metal contamination of a wafer comprises obtaining a contamination level of a first metal and a contamination level of a second metal for the wafer, obtaining a correction value by substituting the obtained contamination level of the second metal into a correlation equation, and obtaining a final contamination level of the first metal, by correcting the contamination level of the obtained first metal based on the correction value.