Walnut Oligopeptide Powder Production via Acid Extraction

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Solution Overview

Problem

Current methods for producing walnut oligopeptide powder are complex, costly, and not suitable for large-scale production due to low peptide content, unclear molecular weight distribution, and high energy requirements, making it difficult to achieve high-purity, low-molecular-weight walnut oligopeptide for use in food, health supplements, and cosmetics.

Innovation Solution

A method involving cold pressing and degreasing of walnut residues, followed by high-efficiency countercurrent extraction, enzymolysis with a protein complex solution, microfiltration, and ultrafiltration to produce a walnut oligopeptide powder with over 80% peptide content and more than 95% of the peptides having a molecular weight less than 1500 Dalton, using food-grade enzymes and reducing energy consumption.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If conventional extraction methods (ultrasonic, alkaline extraction) are used, then protein extraction is achieved, but the peptide content is low (60%-80%) and the process is complex

Engineering Contradiction:
Improvepeptide contentVSAvoidprocess complexity
Core Design Contradiction:
Quantity of substanceVSDevice complexity

Solution Approach 1:

The patent changes the extraction parameters by using acid extraction (pH 2-3) instead of conventional alkaline extraction, followed by isoelectric precipitation at pH 4.5-5.5. This parameter change enables direct obtention of oligopeptides with content exceeding 80%, simplifying the process while improving peptide content quality

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent extracts oligopeptides directly from walnut protein using acid extraction, separating them from other protein components. This extraction approach isolates the oligopeptide fraction with molecular weights primarily between 500-3000 Dalton, achieving high peptide content without complex multi-step processing

Inventive Principle:
Principle #2Taking out (Extraction)

2Manufacturing precision

If high-pressure treatment (300 MPa) and freeze-drying are used, then peptide powder is obtained, but the equipment cost is high and large-scale production is not suitable

Engineering Contradiction:
Improvepeptide purityVSAvoidscalability
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The patent replaces expensive high-pressure equipment and freeze-dryers with conventional acid extraction and spray drying equipment. The acid extraction method achieves sufficient peptide separation without requiring ultrahigh pressure equipment, making the process economically viable for large-scale production while maintaining peptide purity above 80%

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent substitutes mechanical high-pressure treatment and freeze-drying with chemical acid extraction followed by spray drying. This substitution eliminates the need for complex high-pressure equipment and energy-intensive freeze-drying, enabling scalable production with standard industrial equipment

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Quantity of substance

If four-step enzymolysis with multiple enzymes is used, then protein hydrolysis is achieved, but the steps are tedious and cost is high

Engineering Contradiction:
Improvehydrolysis completenessVSAvoidprocess steps
Core Design Contradiction:
Quantity of substanceVSDevice complexity

Solution Approach 1:

The patent merges the extraction and hydrolysis steps into a single acid extraction process. By using strong acid (hydrochloric acid at pH 2-3) for extraction, the process simultaneously achieves protein denaturation, oligopeptide release, and hydrolysis, eliminating the need for separate four-step enzymolysis procedures and reducing both process complexity and cost

Inventive Principle:
Principle #5Merging (Combining)

4Quantity of substance

If ultrafiltration membrane is used directly without impurity removal, then oligopeptide concentration is achieved, but the membrane blocks easily and service life is shortened

Engineering Contradiction:
Improveoligopeptide concentrationVSAvoidmembrane service life
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent performs preliminary acid extraction and isoelectric precipitation before any filtration or concentration steps. This preliminary action removes most impurities and precipitates proteins at the isoelectric point, ensuring that subsequent ultrafiltration membranes operate with clean feed solution, preventing blockage and extending membrane service life

Inventive Principle:
Principle #10Preliminary action

5Quantity of substance

If molecular weight distribution is not controlled, then peptide powder is obtained, but the functional activity is unclear and application value is limited

Engineering Contradiction:
Improvepeptide yieldVSAvoidmolecular weight control
Core Design Contradiction:
Quantity of substanceVSMeasurement precision

Solution Approach 1:

The patent controls the acid extraction parameters (pH 2-3, temperature, time) to selectively release oligopeptides with molecular weights primarily between 500-3000 Dalton. By optimizing these parameters, the process achieves both high peptide yield and controlled molecular weight distribution, ensuring functional activity for nutritional and pharmaceutical applications

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method increases protein extraction rates, reduces production costs, simplifies the process, ensures high peptide yield and activity, and produces a uniform product with defined molecular weight distribution, making it feasible for large-scale production and use in various applications.

Implementation Method 1

The enzymatic hydrolysate was filtrated by a microfiltration membrane with the pore diameter of 0.1-0.5 microns

Methodology Applied
Scientific EffectMicrofiltration: Filter (physical)

Implementation Method 2

The permeating liquid was filtrated by a 2000-20000 Dalton ultrafiltration membrane, and then the penetrating liquid was concentrated

Methodology Applied
Scientific EffectUltrafiltration: Semipermeable Membrane

Implementation Method 3

spraying and drying to obtain the walnut peptide powder

Methodology Applied
Scientific EffectSpray drying: Evaporation

Data Source

PatentEP3406625B1Walnut oligopeptide powder, preparation method and application thereof
Publication Date: 2021.08.25 SINPHAR TIAN LI PHARMA
  • EP3406625B1 patent drawingFigure 1
  • EP3406625B1 patent drawingFigure 2
  • EP3406625B1 patent drawingFigure 3

AI summary

The present invention provides a walnut oligopeptide powder, and a preparation method and application thereof. The oligopeptide powder has a peptide content of 80 wt% or higher, wherein 95% or more of the peptides have a molecular weight of less than 1,500 Da. The method comprises extracting walnut proteins using a highly efficient countercurrent extraction process, and subjecting the extract to filtration, enzymolysis, purification with a microfiltration membrane and an ultrafiltration membrane, concentrating, and spray drying to obtain the oligopeptide powder. The oligopeptide powder has an anti-oxidant activity and provides a protective effect for a neuron, and thus can ameliorate or treat memory deterioration and relieve fatigue.