Low-Temperature Ware Wash Detergent for Hard Water Scale Control

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Solution Overview

Problem

Conventional ware wash detergents, especially those used in institutional and commercial settings with hard water, face challenges with scale build-up due to high alkalinity and elevated temperatures, leading to aesthetic issues and energy inefficiencies, and there is a need for phosphorus-free alternatives that effectively reduce scale formation without using phosphates or NTA, which are environmentally and safety concerns.

Innovation Solution

A phosphorus-free detergent composition comprising aminocarboxylates, water conditioning polymers, and alkalinity sources, used at low temperatures (120°F to 140°F), which reduces or eliminates scale build-up on treated surfaces without surfactants, chelants, or sequestrants, employing aminocarboxylates like methylglycinediacetic acid and water conditioning polymers like polycarboxylates to inhibit scale formation synergistically.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional alkaline detergents are used with hard water, then cleaning effectiveness is improved, but scale build-up increases

Engineering Contradiction:
Improvecleaning effectivenessVSAvoidscale build-up
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent removes phosphates and NTA from the detergent formulation, extracting the harmful components that cause scale build-up while retaining effective cleaning through alternative mechanisms (alkalinity from sodium hydroxide/carbonates, surfactants, and enzymes)

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent changes the chemical composition parameters by eliminating phosphorus-containing compounds and replacing them with phosphate-free alternatives, fundamentally altering how the detergent interacts with hard water minerals to prevent scale formation

Inventive Principle:
Principle #35Parameter changes

2Reliability

If phosphates are used as hardness sequestrants, then scale control is improved, but environmental safety deteriorates

Engineering Contradiction:
Improvescale controlVSAvoidenvironmental harm
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent extracts phosphates from the formulation entirely, eliminating the environmental harm associated with phosphate discharge into waterways while maintaining scale control through alternative ingredients and mechanisms

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent replaces long-term persistent phosphates with biodegradable alternatives that provide temporary scale control during the wash cycle but break down harmlessly, effectively using short-acting substitutes for persistent harmful substances

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Reliability

If NTA-containing aminocarboxylates are used as binding agents, then scale prevention is improved, but safety deteriorates due to carcinogenic concerns

Engineering Contradiction:
Improvescale preventionVSAvoidcarcinogenic risk
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent removes NTA and other carcinogenic aminocarboxylates from the formulation, eliminating the safety hazard while maintaining scale prevention through safe alternative ingredients and mechanisms

Inventive Principle:
Principle #2Taking out (Extraction)

4Reliability

If elevated temperatures are used for ware washing, then cleaning performance is improved, but energy consumption increases

Engineering Contradiction:
Improvecleaning performanceVSAvoidenergy consumption
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The patent modifies the chemical composition to enable effective cleaning at lower temperatures by incorporating temperature-efficient surfactants, enzymes, and builders that maintain cleaning performance without requiring high thermal energy input

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition effectively prevents scale formation on treated surfaces at low temperatures, providing an improved safety profile and energy savings by reducing hard water scale, even in hard water sources, without the need for separate detergency agents like surfactants or enzymes.

Implementation Method 1

phosphorus-free detergent compositions which replace phosphate and/or other phosphorus containing detergent materials... employ aminocarboxylates like methylglycinediacetic acid and water conditioning polymers like polycarboxylates to inhibit scale formation synergistically

Methodology Applied
Scientific EffectChelation:

Implementation Method 2

water conditioning polymers like polycarboxylates to inhibit scale formation synergistically

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS11603511B2Phosphorus free low temperature ware wash detergent for reducing scale build-up
Publication Date: 2023.03.14 ECOLAB USA INC
  • US11603511B2 patent drawing
  • US11603511B2 patent drawing

AI summary

Phosphorus-free detergent compositions are provided. Detergent compositions including an aminocarboxylate, water conditioning agent, source of alkalinity and water beneficially do not require the use of additional surfactants and/or polymers to provide suitable detergency and prevent scale build-up on treated surfaces. The detergent compositions are used with a sanitizer to employ the phosphorus-free detergent compositions for use as low temperature ware wash detergents that beneficially reduce scale build-up. Methods of employing the phosphorus-free detergent compositions are also provided.