Liquefied Waste Plastic Feed for Ethylene Production

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Solution Overview

Problem

Existing methods for upgrading liquefied waste plastic (LWP) face challenges such as high impurity levels, coking tendencies, and the need for hydrogenation, which consumes significant energy and resources.

Innovation Solution

A method involving thermal cracking of a liquefied waste plastic feed with a controlled i-olefins to n-olefins ratio of 3.0 or less, allowing for high yields of ethylene without the need for extensive hydrogenation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-generated harmful factors

If conventional hydrogenation is applied to remove olefins from LWP, then coking tendency is reduced, but hydrogen consumption increases significantly

Engineering Contradiction:
Improvecoking tendencyVSAvoidhydrogen consumption
Core Design Contradiction:
Object-generated harmful factorsVSUse of energy by moving object

Solution Approach 1:

The invention changes the compositional parameters of the LWP feed by controlling the i-olefins to n-olefins ratio to be 3.0 or less. This parameter change allows the feed to be directly suitable for steam cracking without requiring hydrogenation treatment, thereby reducing coking tendency while avoiding significant hydrogen consumption.

Inventive Principle:
Principle #35Parameter changes

2Quantity of substance

If extensive hydrogenation is performed to purify LWP, then impurity levels decrease, but energy consumption and production costs increase

Engineering Contradiction:
Improveimpurity levelVSAvoidenergy consumption
Core Design Contradiction:
Quantity of substanceVSUse of energy by moving object

Solution Approach 1:

The invention changes the compositional parameters of the LWP feed by controlling the i-olefins to n-olefins ratio to be 3.0 or less. This parameter change allows the feed to be directly suitable for steam cracking without requiring hydrogenation treatment, thereby reducing impurity levels while avoiding significant energy consumption.

Inventive Principle:
Principle #35Parameter changes

3Device complexity

If LWP with high i-olefins content is used for steam cracking, then process simplicity is maintained, but coking tendency increases and run lengths decrease

Engineering Contradiction:
Improveprocess complexityVSAvoidcoking tendency
Core Design Contradiction:
Device complexityVSObject-generated harmful factors

Solution Approach 1:

The invention changes the compositional parameters of the LWP feed by controlling the i-olefins to n-olefins ratio to be 3.0 or less. This parameter change reduces coking tendency and extends run lengths while maintaining process simplicity, as no additional hydrogenation units are required.

Inventive Principle:
Principle #35Parameter changes

4Adaptability or versatility

If conventional steam cracking is applied to LWP without composition control, then production flexibility is maintained, but ethylene yield varies significantly

Engineering Contradiction:
Improveproduction flexibilityVSAvoidethylene yield
Core Design Contradiction:
Adaptability or versatilityVSProductivity

Solution Approach 1:

The invention changes the compositional parameters of the LWP feed by controlling the i-olefins to n-olefins ratio to be 3.0 or less. This parameter change ensures high and stable ethylene yields while maintaining production flexibility, as the controlled composition allows direct feeding to steam crackers without additional processing steps.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method achieves high yields of valuable products like ethylene while reducing coking tendencies and minimizing hydrogen consumption, thereby enhancing the sustainability and efficiency of the upgrading process.

Implementation Method 1

a step of thermally cracking the liquefied waste plastic feed in a thermal cracking reactor

Methodology Applied
Scientific EffectThermal cracking: Pyrolysis

Data Source

PatentUS20250034457A1Waste plastic-based thermal cracking feed and method for upgrading the same
Publication Date: 2025.01.30 NESTE OYJ
  • US20250034457A1 patent drawing

AI summary

The disclosure relates to a method for upgrading liquefied waste plastic, wherein the method includes a step of providing a liquefied waste plastic feed, a step of thermally cracking the liquefied waste plastic feed in a thermal cracking reactor, and a step of separating at least a fraction including ethylene from the effluent of the thermal cracking reactor, wherein the liquefied waste plastic feed has a content ratio of i-olefins to n-olefins of 3.0 or less. The disclosure also provides a liquefied waste plastic feed for thermal cracking.