Watch Component Color Coating With Titanium Adhesion Layer

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Solution Overview

Problem

Existing methods for adhering lacquers or paints to silicon, silicon oxide, or glass surfaces in watch components are temporary and isotropic, failing to provide long-term adhesion and precise application to specific areas.

Innovation Solution

A method involving the application of a thin titanium adhesion layer followed by roughening the surface and using physical vapor deposition (PVD) to ensure long-term adhesion and precise application of colored coatings, such as paint, lacquer, or varnish, with optional additional metal layers for aesthetic enhancement.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If oxygen plasma treatment is applied to the surface, then adhesion of lacquer or paint is improved, but the surface treatment effect is temporary and requires immediate painting

Engineering Contradiction:
Improveadhesion of colored layerVSAvoidduration of surface treatment effect
Core Design Contradiction:
ReliabilityVSDuration of action of moving object

Solution Approach 1:

A metal layer (such as titanium) is deposited on the substrate surface in advance through PVD or CVD processes, creating a permanent adhesion-promoting layer before the colored layer is applied. This preliminary metal layer deposition ensures long-term adhesion effectiveness, allowing the colored layer to be applied at any time without requiring immediate painting after surface treatment.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

A metal intermediate layer is introduced between the substrate (glass, silicon, or oxidized silicon) and the colored layer (lacquer or paint). This intermediate metal layer acts as a mediator that provides both mechanical anchoring and chemical bonding sites, significantly improving the adhesion of the colored layer compared to direct application on the substrate.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If chemical adhesion promoter is used, then adhesion duration is extended compared to plasma treatment, but the treatment still has limited time effectiveness

Engineering Contradiction:
Improveadhesion durationVSAvoideffective treatment time window
Core Design Contradiction:
ReliabilityVSDuration of action of moving object

Solution Approach 1:

The metal layer is deposited on the substrate surface in advance through PVD or CVD processes, creating a permanent adhesion-promoting layer before the colored layer is applied. This preliminary metal layer deposition ensures long-term adhesion effectiveness, allowing the colored layer to be applied at any time without requiring immediate painting after surface treatment.

Inventive Principle:
Principle #10Preliminary action

3Ease of manufacture

If isotropic surface treatment is applied, then entire surface is treated uniformly, but selective treatment of specific surface areas cannot be achieved

Engineering Contradiction:
Improveuniform surface treatmentVSAvoidselective surface treatment capability
Core Design Contradiction:
Ease of manufactureVSAdaptability or versatility

Solution Approach 1:

The metal layer is deposited selectively on specific areas of the substrate surface using localized PVD or CVD techniques, or by using masks to define the treatment zones. This allows different regions of the substrate to have different properties: some areas with metal layer for adhesion and coloring, and other areas without metal layer maintaining their original characteristics.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Achieves long-term adhesion and precise application of colored coatings to specific areas of watch components, preventing edge effects and maintaining mechanical and thermal properties.

Implementation Method 1

As soon as the titanium comes into contact with an oxygen source such as air or water, a passive oxide layer a few nanometers thick forms instantly.

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 2

A process involving a titanium bonding layer deposited via physical vapor deposition (PVD) or chemical vapor deposition (CVD)

Methodology Applied
Scientific EffectPhysical vapor deposition: Physical Vapour Deposition

Implementation Method 3

A process involving a titanium bonding layer deposited via physical vapor deposition (PVD) or chemical vapor deposition (CVD)

Methodology Applied
Scientific EffectChemical vapor deposition: Chemical Vapour Deposition

Data Source

PatentEP3764167B1Method for obtaining a timepiece component in which the surface is at least partially covered with a coloured layer
Publication Date: 2026.04.29 PATEK PHILIPPE SA
  • EP3764167B1 patent drawingFigure 1~2
  • EP3764167B1 patent drawingFigure 3~5

AI summary

The process for obtaining a colored surface of a watch component comprises the following steps: a) Depositing a layer of metal onto the exposed area of ​​said surface by PVD or CVD, the metal being selected from titanium, chromium, tantalum, their oxides and nitrides, as well as alloys of these metals. b) Applying a paint, lacquer, or varnish of its own color to the metal layer. Said surface is a silicon, oxidized silicon, glass, or metallic glass surface.