Water-absorbing agent feed rate stability

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Solution Overview

Problem

Water-absorbing agents exhibit unstable feed rates when fed using certain feeders, such as BSP-type apparatuses, due to changes in temperature and humidity, and existing indicators like Carr's flowability index are not effective in predicting feed rate fluctuations.

Innovation Solution

A water-absorbing agent with specific properties, including a polyacrylic acid-based resin, a polyvalent metal salt, and controlled particle size distribution, is developed to stabilize feed rates by using a correlation equation that considers bulk density, compressibility rate, and angle of repose, ensuring a high K-index and low moisture absorption blocking ratio.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If a BSP-type apparatus is used to feed water-absorbing agent, then the feed rate can be controlled, but the feed rate becomes unstable due to temperature and humidity changes

Engineering Contradiction:
Improvefeed rate controlVSAvoidfeed rate stability
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent modifies the physical parameters of the water-absorbing agent by controlling particle size distribution (D50: 200-600 μm, σ: 0.20-0.50) and adding specific additives (polyvalent metal salts, waxes, oils) to change the material's bulk density, compressibility rate, and angle of repose, making the feed rate stable despite temperature and humidity variations

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces new evaluation parameters (K-index, moisture absorption blocking ratio, bulk density, compressibility rate, angle of repose) that provide feedback on the water-absorbing agent's properties, allowing optimization of the material to ensure stable feeding with BSP-type apparatus

Inventive Principle:
Principle #23Feedback

2Measurement precision

If Carr's flowability index is used to predict feed rate stability, then flowability can be assessed, but it fails to predict feed rate fluctuations for BSP-type apparatus

Engineering Contradiction:
Improveflowability assessmentVSAvoidfeed rate prediction accuracy
Core Design Contradiction:
Measurement precisionVSReliability

Solution Approach 1:

The patent extracts the limitations of Carr's flowability index for BSP-type apparatus feeding and introduces new evaluation parameters (K-index, moisture absorption blocking ratio, bulk density, compressibility rate, angle of repose) that are specifically relevant to positive displacement pumping, providing accurate prediction of feed rate stability

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent changes the evaluation parameters from Carr's flowability index to a new set of parameters (K-index, moisture absorption blocking ratio, bulk density, compressibility rate, angle of repose) that are specifically suited for assessing feed rate stability with BSP-type apparatus

Inventive Principle:
Principle #35Parameter changes

3Adaptability or versatility

If water-absorbing agent particles aggregate due to temperature and humidity changes, then the material adapts to environmental conditions, but the feed rate becomes unstable

Engineering Contradiction:
Improveenvironmental adaptationVSAvoidfeed rate consistency
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent converts the harmful effect of temperature and humidity changes (which cause aggregation and adhesion) into a beneficial outcome by adding specific additives (polyvalent metal salts, waxes, oils) that control moisture absorption and reduce adhesion, allowing the material to adapt to environmental changes while maintaining stable feed rate

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The patent creates a composite water-absorbing agent material by combining polyacrylic acid-based resin with specific additives (polyvalent metal salts, waxes, oils) to produce a material with controlled bulk density, compressibility rate, and angle of repose that maintains feed rate stability across varying environmental conditions

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides a stable and accurate feed rate with minimal fluctuations, even under varying conditions, enhancing the reliability of water-absorbing agents in absorbent articles.

Implementation Method 1

Water-absorbing resin (Super Absorbent Polymer, or SAP) is a water-swellable, water-insoluble polymer gelling agent

Methodology Applied
Scientific EffectCapillary action: Capillary Action

Implementation Method 2

Water-absorbing resin is a water-swellable, water-insoluble polymer gelling agent

Methodology Applied
Scientific EffectHydrogel formation: Hydrogel

Data Source

PatentEP3711722B1Absorption agent and absorbent article
Publication Date: 2024.06.19 NIPPON SHOKUBAI CO LTD
  • EP3711722B1 patent drawingFigure 1~2
  • EP3711722B1 patent drawingFigure 3~4
  • EP3711722B1 patent drawingFigure 5~6

AI summary

Provided is a water-absorbing agent that causes no or little fluctuation of feed rate when fed with use of a feeder. A water-absorbing agent containing a water-absorbing resin as a main component, the water-absorbing agent satisfying the following (a) and (b): (a) K-index is 70 or more; and (b) Moisture absorption blocking ratio, after 30 minutes of standing at a temperature of 25°C and a relative humidity of 80%RH, is 70 weight% or less, the K-index being defined by the following equation: K-index = 100 - (-438 + 3.6 x angle of repose + 3.5 x angle of difference + 7.9 x compressibility rate + 290 x bulk density (EDANA method)).