Water-Based Amine Curing Agent for Low Viscosity Coatings

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Solution Overview

Problem

Conventional solvent-free curing agents for epoxy resin systems face challenges such as high viscosity, poor substrate wetting, short pot life, and manufacturing difficulties, along with environmental concerns like VOC emissions, toxicity, and flammability.

Innovation Solution

A water-based amine curing agent is developed as a reaction product of an aqueous epoxy dispersion and a cycloaliphatic polyamine compound, which can be formed with or without a surfactant, offering low viscosity, improved pot life, and low VOC content, suitable for use in two-component coating systems.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If solvent-free curing agents are used, then environmental pollution and health hazards are reduced, but viscosity becomes too high making application difficult

Engineering Contradiction:
ImproveVOC emissions and health hazardsVSAvoidviscosity and applicability
Core Design Contradiction:
Object-affected harmful factorsVSEase of operation

Solution Approach 1:

The patent introduces water as a solvent to change the physical state of the curing agent system, transforming it from a high-viscosity solvent-free form to a water-based dispersion with reduced viscosity. This parameter change (adding water) enables easier application while maintaining the environmental benefits of reduced VOC emissions, as water replaces organic solvents.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses water as an intermediary substance to mediate between the curing agent and the application process. Water acts as a carrier that reduces viscosity and facilitates application, while being environmentally benign. The water-based dispersion serves as an intermediate form that bridges the gap between the solid curing agent and the final cured product.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Ease of operation

If water-based curing agents are used, then viscosity is reduced and application is improved, but pot life becomes short

Engineering Contradiction:
Improveviscosity and applicabilityVSAvoidpot life
Core Design Contradiction:
Ease of operationVSDuration of action of moving object

Solution Approach 1:

The patent optimizes the water content parameter in the curing agent formulation to balance viscosity reduction with pot life extension. By controlling the amount of water added and the timing of the reaction between water and epoxy groups, the patent achieves a formulation that maintains low viscosity for easy application while extending the working pot life through controlled reaction kinetics.

Inventive Principle:
Principle #35Parameter changes

3Object-affected harmful factors

If high solids content is achieved, then environmental impact is reduced, but viscosity increases making processing difficult

Engineering Contradiction:
Improveenvironmental impactVSAvoidviscosity and processability
Core Design Contradiction:
Object-affected harmful factorsVSEase of operation

Solution Approach 1:

The patent utilizes water as a green solvent to enable high solids content formulations without the viscosity penalties typically associated with high concentration systems. By replacing organic solvents with water, the patent achieves both high solids content (reducing environmental impact) and low viscosity (maintaining processability), as water provides effective solvation and flow properties.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The water-based amine curing agent provides stable viscosity, easy application, and high solids content, resulting in transparent, high-gloss coatings with enhanced drying rates and reduced environmental impact.

Implementation Method 1

A water-based amine curing agent for a curable resin which is a reaction product of: (A) an aqueous epoxy dispersion; and (B) a polyamine component consisting of a cycloaliphatic polyamine compound

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Data Source

PatentEP2718355B1Water-based amine curing agents for curable resin systems
Publication Date: 2016.11.02 HUNTSMAN ADVANCED MATERIALS AMERICAS LLC
  • EP2718355B1 patent drawing
  • EP2718355B1 patent drawing
  • EP2718355B1 patent drawing

AI summary

The present disclosure relates to a water-based amine curing agent which is a reaction product obtained from the reaction of an aqueous epoxy resin dispersion and a polyamine component. The water-based amine curing agent may be used as part of a two component coating system in the curing of modified or unmodified liquid or pre- dispersed curable resin.