Water-Based Conductive Ink for High-Speed RFID Antennas

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Solution Overview

Problem

Current electrically conductive inks face challenges such as high electrical resistivity, long drying and curing times, and incompatibility with low-cost substrates like paper and cardboard due to high thermal requirements, which limit their use in high-speed printing applications for electronic circuitry and RFID antennas.

Innovation Solution

A water-based conductive ink composition using a styrene-acrylic copolymer matrix with anionic wetting agents to disperse silver particles, achieving high conductivity and low sheet resistance, suitable for high-speed printing on low-cost substrates with reduced thermal energy requirements.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If solvent-based thick film systems are used to achieve high conductivity, then electrical resistivity is reduced, but drying and curing time increases and thermal energy consumption increases

Engineering Contradiction:
Improveelectrical conductivityVSAvoiddrying and curing time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The patent changes the fundamental parameter of the solvent system from organic solvent to water, enabling rapid evaporation at ambient or low temperatures. This parameter change allows the ink to achieve high conductivity without requiring long drying times or high thermal energy input, as water can evaporate quickly under mild conditions compared to organic solvents

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces the thermal curing mechanism with a water-based evaporation mechanism. Instead of relying on high-temperature thermal processes to dry and cure the ink, the system uses the evaporative properties of water to achieve rapid drying at ambient or low temperatures, substituting a thermal field with a phase-change process

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Reliability

If high drying temperatures are used to achieve proper ink curing, then conductivity is improved, but substrate compatibility deteriorates for low-cost substrates

Engineering Contradiction:
Improveelectrical conductivityVSAvoidsubstrate compatibility
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent changes the drying temperature parameter from high temperature to ambient or low temperature by using water as the solvent. Water's low boiling point and high vapor pressure at room temperature enable the ink to dry and cure properly without exposing substrates to high thermal stresses, thereby expanding compatibility to include paper, cardboard, and low-melting-point plastics

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses water as an intermediary carrier that mediates between the conductive particles and the substrate. Water provides a benign drying environment that protects temperature-sensitive substrates while still enabling proper ink curing, acting as a protective intermediary that allows the use of low-cost substrates without compromising electrical performance

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If conductive powder concentration is increased to achieve high conductivity, then electrical resistivity is reduced, but manufacturing cost increases

Engineering Contradiction:
Improveelectrical conductivityVSAvoidmanufacturing cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent changes the particle distribution parameter by using water as a dispersing medium. Water provides excellent wetting and dispersing properties for conductive particles, allowing them to be evenly distributed at lower concentrations while still achieving high conductivity. This reduces the amount of expensive conductive powder needed compared to organic solvent-based systems

Inventive Principle:
Principle #35Parameter changes

4Object-affected harmful factors

If water-based ink is used to reduce environmental impact, then ecological advantage is improved, but electrical conductivity deteriorates compared to solvent-based systems

Engineering Contradiction:
Improveenvironmental impactVSAvoidelectrical conductivity
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent changes multiple parameters simultaneously: the solvent composition (water-based), particle size distribution, and particle concentration. These parameter changes work together to achieve high conductivity in a water-based system, overcoming the traditional limitation that water-based inks have poor conductivity. The specific parameter组合 allows the ink to maintain high conductivity while being environmentally friendly

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ink provides a UHF RFID antenna read range of at least 3 meters with a sheet resistance of less than 120 milliohm/square, maintaining print resolution and substrate adhesion, while being environmentally friendly and cost-effective.

Implementation Method 1

a water soluble copolymer of styrene and (meth)acrylic acid or a salt thereof, and an anionic wetting agent, which synergistically disperses the conductive particles

Methodology Applied
Scientific EffectDispersion: Dispersion (of waves)

Implementation Method 2

aqueous conductive inks... offer significant ecological advantages over solvent-based compositions, as the latter release solvents into the atmosphere on drying

Methodology Applied
Scientific EffectEvaporation: Evaporation

Data Source

PatentEP2059568B1Highly conductive water-based ink
Publication Date: 2014.09.03 SUN CHEMICAL CORP

AI summary

Disclosed is a conductive composition which can be used to form an aqueous conductive ink with increased conductivity. A film of the dry ink having a thickness of 5 microns or less has a surface roughness of less than 1.5 times the surface roughness of a cellulosic-based substrate which it coats. The aqueous conductive composition contains conductive particles, preferably silver, an anionic wetting agent and a styrene-acrylic copolymer. The composition is highly conductive and requires reduced drying energy. In addition, it may be applied to low cost substrates by high speed printing processes.