Water-Based Herbicide Compositions with Surfactant-Enhanced Rainfastness

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Solution Overview

Problem

Existing herbicidal formulations face challenges in achieving adequate rainfastness and herbicidal efficacy, requiring significant experimental work to develop suitable compositions, especially for water-based formulations with water-soluble active ingredients.

Innovation Solution

Compositions comprising water-soluble herbicidal ingredients combined with specific surfactants and esters, such as C6-C16 fatty alcohol polyethylene glycol ether sulfates, C6-C16 alkylpolyglycosides, and C10-C18 fatty alkyl amine ethoxylates, along with optional esters and other constituents, to enhance rainfastness and herbicidal properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If water-based formulations are used to reduce organic solvents, then environmental friendliness and safety improve, but distribution of constituents and formulation stability deteriorate

Engineering Contradiction:
Improveorganic solvent contentVSAvoidformulation stability
Core Design Contradiction:
Object-affected harmful factorsVSStability of the object's composition

Solution Approach 1:

The patent combines multiple surfactant types (nonionic surfactants with ethoxylate groups and anionic surfactants) in a water-based formulation to create a composite surfactant system. This composite approach allows the formulation to achieve both environmental friendliness (water-based) and adequate distribution/stability through synergistic interactions between different surfactant classes

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes specific parameters including the ethoxylate chain length (5-20 units), surfactant concentration ratios, and pH levels to achieve stable water-based formulations. By carefully controlling these parameters, the formulation maintains constituent distribution without requiring organic solvents

Inventive Principle:
Principle #35Parameter changes

2Reliability

If adjuvants are added to improve rainfastness, then pesticide retention on leaf surface improves, but formulation complexity and cost increase

Engineering Contradiction:
ImproverainfastnessVSAvoidformulation complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent designs surfactants that perform multiple functions simultaneously: they act as emulsifiers for water-based formulation stability, penetration enhancers for herbicide uptake, and rainfastness agents for physical retention on leaf surfaces. This multi-functionality reduces the need for separate adjuvant additions and simplifies the overall formulation

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent combines the functions of multiple traditional adjuvants into a single integrated surfactant system. The surfactant mixture merges penetration enhancement, emulsification, and rainfastness properties into one formulation package, reducing complexity compared to using separate adjuvant products

Inventive Principle:
Principle #5Merging (Combining)

3Ease of manufacture

If traditional herbicide formulations are used, then manufacturing simplicity is maintained, but rainfastness and herbicidal efficacy deteriorate

Engineering Contradiction:
Improvemanufacturing simplicityVSAvoidherbicidal efficacy
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent modifies key formulation parameters by switching from oil-based to water-based continuous phases, optimizing surfactant concentrations and types, and adjusting pH levels. These parameter changes improve rainfastness and efficacy while maintaining relatively simple manufacturing processes through conventional mixing and stabilization techniques

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The compositions exhibit improved rainfastness and herbicidal activity, maintaining effectiveness even after rainfall, with high bioavailability and stability, suitable for use in crop protection.

Implementation Method 1

comprising water-soluble herbicidal ingredients combined with specific surfactants and esters, such as C6-C16 fatty alcohol polyethylene glycol ether sulfates, C6-C16 alkylpolyglycosides, and C10-C18 fatty alkyl amine ethoxylates

Methodology Applied
Scientific EffectSurface tension reduction: Surfactant

Implementation Method 2

one or more esters selected from the group consisting of (c1) R1COOR2 wherein R1 is a C1-C20 alkyl group and R2 is a C2-C20 alkyl group

Methodology Applied
Scientific EffectPenetration enhancement: Permeation

Data Source

PatentEP3829302B1Herbicide compositions with improved properties
Publication Date: 2025.08.06 BAYER AG
  • EP3829302B1 patent drawing
  • EP3829302B1 patent drawing
  • EP3829302B1 patent drawing

AI summary

The present invention relates to the technical field of crop protection compositions (formulations) comprising water soluble herbicidal active ingredients and certain further constituents having improved properties, in particular regarding rainfastness and/or herbicidal efficacy. The invention also relates to methods of manufacturing such compositions and the use of such compositions.