Water-Based Ink Color Stability via Boron Mediators
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Solution Overview
Problem
High weather resistance magenta dyes used in water-based ink-jet inks cause color changes when mixed with yellow and cyan inks, leading to a weakened color tone and greenish tint in process black recordings due to humidity effects.
Innovation Solution
Incorporating a boron compound and amino polycarboxylic acid into the water-based ink-jet inks, specifically a dye represented by a general formula that includes specific alkyl, aryl, and heterocyclic groups, to suppress color changes and improve the ink's ruggedness.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Reliability
If high weather resistance magenta dye is used, then light resistance and ozone resistance are improved, but diffusibility relative to recording medium changes under humidity conditions
Solution Approach 1:
The patent introduces a specific compound (formula 1) as an intermediary substance that mediates between the high weather resistance magenta dye and the recording medium. This compound contains a nitrogen-containing six-membered aromatic ring with specific substituents (R1-R7) that enable it to interact with both the dye molecules and the recording medium, thereby maintaining stable diffusibility while preserving the dye's weather resistance properties.
Solution Approach 2:
The patent modifies the chemical parameters of the ink formulation by introducing a specifically structured compound with defined molecular characteristics (nitrogen-containing aromatic ring, specific substituent groups R1-R7). This parameter change in the ink composition alters the interaction dynamics between the dye and recording medium, stabilizing diffusibility under varying humidity conditions while maintaining the dye's inherent weather resistance.
2Reliability
If high weather resistance magenta dye is used in process black, then light resistance is improved, but color tone is weakened and green tinge appears
Solution Approach 1:
The compound of formula 1 acts as a mediator that prevents excessive diffusion of the magenta dye while maintaining proper color mixing in process black. By controlling the interaction between the dye and recording medium, it ensures that magenta, yellow, and cyan inks mix accurately to produce neutral black without green tinges, while still providing the light resistance benefits of high weather resistance dyes.
Solution Approach 2:
The patent changes the chemical parameters of the magenta ink formulation by incorporating the specifically structured compound (formula 1). This parameter change optimizes the diffusion characteristics and color mixing properties, enabling process black to achieve accurate neutral tones while maintaining the light resistance provided by high weather resistance dyes.
Data Source
AI summary
The present invention provides a water-based ink for ink-jet recording containing a coloring agent, water, and a water-soluble organic solvent. The coloring agent contains a dye represented by the following general formula (1). The ink further includes a boron compound and at least one of amino polycarboxylic acid and amino polycarboxylate.


