Water-Based Ink Composition for Enhanced Light and Ozone Resistance

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Solution Overview

Problem

Conventional yellow inks for ink-jet recording fail to simultaneously achieve good clearness, color development, storage stability, light resistance, and ozone resistance.

Innovation Solution

A water-based ink composition comprising a specific dye (1) and dye (2), such as C. I. Direct Yellow 86, C. I. Direct Yellow 132, C. I. Direct Yellow 142, or C. I. Direct Yellow 173, with a weight ratio between 6:4 to 9:1, along with a water-soluble organic solvent like glycerin, to enhance preservation stability and light resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If conventional yellow dyes (C.I. Direct Yellow 86, 132, 142, or 173) are used for ink-jet recording, then color development is improved, but preservation stability and light resistance deteriorate

Engineering Contradiction:
Improvecolor developmentVSAvoidpreservation stability
Core Design Contradiction:
Illumination intensityVSReliability

Solution Approach 1:

The patent uses a composite dye system combining two different yellow dyes (C.I. Direct Yellow 86, 132, 142, or 173 with another yellow dye) in specific weight ratios (9:1 to 4:6). This composite approach allows the ink to achieve both good color development and improved preservation stability, as each dye contributes different properties that complement each other.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes the weight ratio parameter of the composite dye system and controls the total dye concentration (0.1-7 wt%) to achieve the desired balance between color development and preservation stability. By adjusting these parameters, the ink formulation achieves simultaneous improvement in both performance aspects.

Inventive Principle:
Principle #35Parameter changes

2Illumination intensity

If conventional yellow dyes are used for ink-jet recording, then color development is improved, but light resistance deteriorates

Engineering Contradiction:
Improvecolor developmentVSAvoidlight resistance
Core Design Contradiction:
Illumination intensityVSObject-affected harmful factors

Solution Approach 1:

The composite dye system combines two yellow dyes with different light resistance characteristics. The specific combination (C.I. Direct Yellow 86, 132, 142, or 173 with another yellow dye in 9:1 to 4:6 weight ratio) creates synergistic effects that improve overall light resistance while maintaining good color development.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent introduces a water-soluble organic solvent as an intermediary substance that mediates between the dye molecules and the recording material. This solvent system (containing polyalcohol and/or carboxylic acid) helps protect the dye from light degradation while maintaining color development properties.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Manufacturing precision

If conventional yellow dyes are used for ink-jet recording, then clearness is improved, but ozone resistance deteriorates

Engineering Contradiction:
ImproveclearnessVSAvoidozone resistance
Core Design Contradiction:
Manufacturing precisionVSObject-affected harmful factors

Solution Approach 1:

The composite dye system provides both clearness and ozone resistance through the synergistic combination of two yellow dyes. The specific dye combination and weight ratio optimization ensure that the ink maintains good clearness while achieving improved ozone resistance that exceeds the average performance of individual dyes.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The water-soluble organic solvent acts as a protective intermediary between the dye and ozone. The solvent system (with polyalcohol and/or carboxylic acid) forms a protective environment that reduces ozone attack on the dye molecules while maintaining the clearness of the recorded image.

Inventive Principle:
Principle #24Intermediary (Mediator)

Data Source

PatentUS8128747B2Water-based ink for ink-jet recording, ink cartridge and ink-jet recording apparatus
Publication Date: 2012.03.06 BROTHER KOGYO KK
  • US8128747B2 patent drawing
  • US8128747B2 patent drawing
  • US8128747B2 patent drawing

AI summary

A water-based ink for ink-jet recording includes a coloring agent, water, and a water-soluble organic solvent. The coloring agent includes the following dye (1) and dye (2). The water-based ink is good in clearness, color development, and preservation stability as well as good in toughness of a recording material recorded using the water-based ink.Dye (1): dye represented by the following general formula (1)Dye (2): at least one dye selected from the group consisting of C. I. Direct Yellow 86, C. I. Direct Yellow 132, C. I. Direct Yellow 142, and C. I. Direct Yellow 173.