Water-Based Ink Dispersibility and Stability

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Solution Overview

Problem

Water-based pigment inks for ink-jet recording using pigment dispersing resins experience instability in discharge and re-dispersibility, leading to warping and white voids during continuous recording, which affects the stability and quality of inkjet printing.

Innovation Solution

A water-based ink formulation incorporating a pigment dispersing resin with an ethylene oxide chain, an anionic surfactant, and a nonionic surfactant, both containing ethylene oxide groups, to enhance dispersibility and re-dispersibility, thereby stabilizing ink discharge and preventing warping and white voids.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If a pigment dispersing resin is used to disperse pigment in water, then the pigment can be dispersed in water, but the discharge stability becomes unstable during continuous recording

Engineering Contradiction:
Improvepigment dispersion stabilityVSAvoiddischarge stability
Core Design Contradiction:
Stability of the object's compositionVSReliability

Solution Approach 1:

The patent uses a composite system combining pigment dispersing resin with specific surfactants (anionic and nonionic types) to achieve both good pigment dispersion and stable discharge performance during continuous recording

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes the molecular structure parameters of the dispersing resin by incorporating ethylene oxide chains and controls the pH value and ionic strength of the ink formulation to improve discharge stability

Inventive Principle:
Principle #35Parameter changes

2Stability of the object's composition

If a pigment dispersing resin is used to disperse pigment in water, then the pigment can be dispersed in water, but re-dispersibility is insufficient

Engineering Contradiction:
Improvepigment dispersion stabilityVSAvoidre-dispersibility
Core Design Contradiction:
Stability of the object's compositionVSEase of manufacture

Solution Approach 1:

The patent introduces surfactants as intermediary substances that facilitate the re-dispersion of pigment particles by reducing surface tension and preventing aggregation, making the re-dispersibility easier to achieve

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent modifies the chemical structure of the dispersing resin by adding ethylene oxide chains which enhance hydrophilicity and improve re-dispersibility through changed interaction parameters with water and pigment particles

Inventive Principle:
Principle #35Parameter changes

3Stability of the object's composition

If conventional pigment dispersing resin is used, then pigment can be dispersed, but warping and white voids occur during continuous recording

Engineering Contradiction:
Improvepigment dispersionVSAvoidrecording quality
Core Design Contradiction:
Stability of the object's compositionVSManufacturing precision

Solution Approach 1:

The patent creates a composite ink formulation combining pigment dispersing resin with specifically selected anionic and nonionic surfactants to prevent warping and white voids while maintaining pigment dispersion

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent adjusts critical parameters including pH value, ionic strength, and molecular structure of the dispersing system to eliminate warping and white void defects during continuous recording

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The formulation improves the stability of ink discharge during continuous recording and enhances re-dispersibility, reducing the occurrence of warping and white voids, resulting in improved printing quality and chromaticness.

Implementation Method 1

a pigment dispersing resin including an ethylene oxide chain; an anionic surfactant including an ethylene oxide group; and a nonionic surfactant including an ethylene oxide group

Methodology Applied
Scientific EffectHydrophilic interaction: Hydrophile

Data Source

PatentEP3150679B1Water based-ink for ink-jet recording
Publication Date: 2018.12.19 BROTHER KOGYO KK
  • EP3150679B1 patent drawingFigure 1
  • EP3150679B1 patent drawing
  • EP3150679B1 patent drawing

AI summary

A water-based ink for ink-jet recording includes: a pigment; water; a pigment dispersing resin including an ethylene oxide chain; and at least one of an anionic surfactant including an ethylene oxide group and a nonionic surfactant including an ethylene oxide group.