Water-Based Ink Formulation for Ejection Stability

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Conventional water-based inks for ink-jet recording face issues with light resistance, water resistance, evaporation characteristics, and ejection stability, particularly due to the elution of compounds from the ink-jet recording apparatus materials into the ink, which can lead to nozzle clogging and poor printing quality.

Innovation Solution

A water-based ink composition comprising self-dispersing pigments, glycerin as a humectant, dipropylene glycol propyl ether as a penetrant, and an acetylene glycol surfactant, optimized within specific weight percentage ranges to enhance printing quality, evaporation characteristics, and ejection stability, while minimizing the elution of apparatus materials into the ink.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If the amount of penetrant is increased to improve printing quality, then printing quality is improved, but evaporation characteristic of the ink is worsened and compounds from rubber members may be eluted into the ink

Engineering Contradiction:
Improveprinting qualityVSAvoidevaporation characteristic
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent changes the chemical parameters of the ink formulation by specifying precise amounts of penetrant (2.0-3.0 wt%), humectant (15-25 wt%), and surfactant (0.1-0.3 wt%), along with using self-dispersing pigments with specific surface treatments. This parameter optimization resolves the contradiction by achieving adequate printing quality while preventing excessive penetrant that would worsen evaporation characteristics and cause rubber elution.

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If the amount of pigment (solid content) is increased to improve printing quality, then printing quality is improved, but evaporation characteristic is worsened and compounds from rubber members may be eluted into the ink

Engineering Contradiction:
Improveprinting qualityVSAvoidelution of rubber member compounds
Core Design Contradiction:
Manufacturing precisionVSObject-generated harmful factors

Solution Approach 1:

The patent optimizes the pigment concentration parameter to 3.5-4.5 wt% solid content and combines it with specific surfactant (0.1-0.3 wt%) and humectant (15-25 wt%) amounts. This balanced parameter set achieves improved printing quality through adequate pigment concentration while preventing harmful rubber elution by maintaining proper evaporation characteristics through the coordinated formulation.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses self-dispersing pigments with specific surface treatments (such as polyvinyl alcohol or polyacrylic acid coatings) as a composite material approach. This allows the pigment to disperse uniformly in water-based ink without requiring excessive penetrant or surfactant, thereby improving printing quality while preventing rubber compound elution.

Inventive Principle:
Principle #40Composite materials

3Reliability

If the amount of humectant, penetrant, and surfactant is adjusted to control viscosity and improve evaporation characteristic, then evaporation characteristic is improved, but ejection stability may be worsened

Engineering Contradiction:
Improveevaporation characteristicVSAvoidejection stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent carefully balances the parameters of humectant (15-25 wt%), penetrant (2.0-3.0 wt%), and surfactant (0.1-0.3 wt%) to achieve optimal viscosity control. This balanced formulation ensures proper evaporation characteristics while maintaining ejection stability, resolving the contradiction between these two requirements.

Inventive Principle:
Principle #35Parameter changes

4Quantity of substance

If water-soluble dye is used as coloring agent to achieve height of chroma and good water solubility, then chroma and water solubility are improved, but light resistance and water resistance of recording material are insufficient

Engineering Contradiction:
Improvechroma and water solubilityVSAvoidlight resistance and water resistance
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent employs self-dispersing pigments with specific surface treatments (such as polyvinyl alcohol or polyacrylic acid coatings) as a composite material alternative to water-soluble dyes. This provides both the desired chroma and water solubility through the pigment dispersion while simultaneously achieving superior light resistance and water resistance that dyes cannot provide.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ink composition achieves improved printing quality, evaporation characteristics, and ejection stability, with a balanced formulation that maintains a high proportion of self-dispersing pigment and appropriate levels of humectant and surfactant, preventing nozzle clogging and ensuring consistent ink performance.

Implementation Method 1

comprises a self-dispersing pigment, water, a water-soluble organic solvent, and an acetylene glycol surfactant

Methodology Applied
Scientific EffectSelf-dispersion: Dispersion (of waves)

Implementation Method 2

The water-soluble organic solvent comprises glycerin and dipropylene glycol propyl ether. An amount of the glycerin relative to a total amount of the ink is in the range of about 15 wt % to about 25 wt %

Methodology Applied
Scientific EffectHumectant action: Absorption (physical)

Implementation Method 3

an acetylene glycol surfactant. An amount of the acetylene glycol surfactant relative to a total amount of the ink is in a range of about 0.1 wt % to about 0.3 wt %

Methodology Applied
Scientific EffectSurfactant action: Surfactant

Implementation Method 4

The water-soluble organic solvent comprises glycerin and dipropylene glycol propyl ether. An amount of the dipropylene glycol propyl ether relative to a total amount of the ink is in the range of about 2.0 wt % to about 3.0 wt %

Methodology Applied
Scientific EffectPenetration: Permeation

Data Source

PatentUS8062412B2Water-based ink for ink-jet recording, ink cartridge and ink-jet recording apparatus
Publication Date: 2011.11.22 BROTHER KOGYO KK
  • US8062412B2 patent drawing
  • US8062412B2 patent drawing
  • US8062412B2 patent drawing

AI summary

A water-based ink for ink-jet recording includes a self-dispersing pigment, water, a water-soluble organic solvent, and an acetylene glycol surfactant. An amount of the self-dispersing pigment (solid content) relative to a total amount of the ink is in a range of about 3.5 wt % to about 4.5 wt %. The water-soluble organic solvent includes glycerin and dipropylene glycol propyl ether, an amount of the glycerin relative to a total amount of the ink is in a range of about 15 wt % to about 25 wt %, and an amount of the dipropylene glycol propyl ether relative to a total amount of the ink is in a range of about 2.0 wt % to about 3.0 wt %. An amount of the acetylene glycol surfactant relative to a total amount of the ink is in a range of about 0.1 wt % to about 0.3 wt %.