Water-Based Ink Fixability on Impermeable Substrates

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Solution Overview

Problem

Current water-based inks lack satisfactory fixability, high-speed printability, discharging reliability, scratch resistance, and storage stability when used on impermeable base materials, and existing solvent-based inks pose environmental hazards.

Innovation Solution

A water-based ink formulation containing organic solvents with specific Hansen solubility parameters and diol compounds, which improve fixability and discharging reliability, and include resin particles for enhanced scratch resistance and storage stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If water-based inks are used on impermeable base materials, then environmental safety is improved, but fixability deteriorates

Engineering Contradiction:
Improveenvironmental safetyVSAvoidfixability
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent applies parameter changes by carefully selecting organic solvents with specific Hansen solubility parameters (δH: 4.1-9.5 MPa^1/2, boiling point ≥170°C) and controlling their content (5-60 mass%). This optimization of chemical parameters enables water-based ink to achieve satisfactory fixability on impermeable base materials while maintaining environmental safety

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite materials by combining water, specifically selected organic solvents, color materials, and resin particles into a multi-component ink formulation. This composite approach leverages the advantages of each component to achieve both environmental friendliness and excellent fixability on impermeable substrates

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If water-based inks are used, then environmental safety is improved, but high-speed printability deteriorates

Engineering Contradiction:
Improveenvironmental safetyVSAvoidhigh-speed printability
Core Design Contradiction:
Object-affected harmful factorsVSProductivity

Solution Approach 1:

The patent optimizes viscosity parameters by selecting organic solvents with specific boiling points (≥170°C) and controlling solvent content (5-60 mass%). This parameter optimization ensures appropriate ink flow characteristics for high-speed inkjet printing while maintaining water-based environmental safety

Inventive Principle:
Principle #35Parameter changes

3Object-affected harmful factors

If water-based inks are used, then environmental safety is improved, but discharging reliability deteriorates

Engineering Contradiction:
Improveenvironmental safetyVSAvoiddischarging reliability
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent controls the viscosity and surface tension parameters of the ink by selecting organic solvents with specific Hansen solubility parameters and boiling points, and by optimizing their content (5-60 mass%). This parameter control ensures stable ink discharge reliability in water-based formulations

Inventive Principle:
Principle #35Parameter changes

4Object-affected harmful factors

If water-based inks are used, then environmental safety is improved, but scratch resistance deteriorates

Engineering Contradiction:
Improveenvironmental safetyVSAvoidscratch resistance
Core Design Contradiction:
Object-affected harmful factorsVSStrength

Solution Approach 1:

The patent enhances scratch resistance by incorporating resin particles into the water-based ink formulation. The combination of water, organic solvents, color materials, and resin particles creates a composite ink system that provides both environmental safety and improved mechanical durability

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes the molecular weight and content parameters of resin particles to enhance the mechanical properties of the dried ink film, thereby improving scratch resistance while maintaining the water-based environmentally friendly formulation

Inventive Principle:
Principle #35Parameter changes

5Object-affected harmful factors

If water-based inks are used, then environmental safety is improved, but storage stability deteriorates

Engineering Contradiction:
Improveenvironmental safetyVSAvoidstorage stability
Core Design Contradiction:
Object-affected harmful factorsVSStability of the object's composition

Solution Approach 1:

The patent improves storage stability by carefully selecting organic solvents with specific Hansen solubility parameters (δH: 4.1-9.5 MPa^1/2) and boiling points (≥170°C), and by controlling their content (5-60 mass%). This parameter optimization prevents phase separation and precipitation during storage while maintaining environmental safety

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ink achieves excellent fixability, high-speed printability, discharging reliability, and scratch resistance while maintaining storage stability, comparable to solvent-based inks, and is environmentally friendly.

Implementation Method 1

The plurality of organic solvents contain at least one compound having a hydrogen bond term δH, which is a Hansen solubility parameter, of 4.1 MPa1/2 or higher but 9.5 MPa1/2 or lower and a boiling point of 170° C. or higher

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 2

at least one compound having a hydrogen bond term δH, which is a Hansen solubility parameter, of 4.1 MPa1/2 or higher but 9.5 MPa1/2 or lower

Methodology Applied
Scientific EffectHydrogen bonding: Chemical Bonding

Implementation Method 3

at least one diol compound containing 3 or 4 carbon atoms

Methodology Applied
Scientific EffectMolecular structure interaction:

Data Source

PatentUS11472977B2Ink, inkjet recording method, inkjet recording apparatus, and recorded matter
Publication Date: 2022.10.18 RICOH CO LTD
  • US11472977B2 patent drawing
  • US11472977B2 patent drawing

AI summary

Provided is an ink containing water, a plurality of organic solvents, a color material, and resin particles, wherein the plurality of organic solvents contain at least one compound having a hydrogen bond term δH, which is a Hansen solubility parameter, of 4.1 MPa1/2 or higher but 9.5 MPa1/2 or lower and a boiling point of 170° C. or higher and at least one diol compound containing 3 or 4 carbon atoms.